Atom transfer radical polymerization: billion times more active catalysts and new initiation systems

TG Ribelli, F Lorandi, M Fantin… - Macromolecular rapid …, 2019 - Wiley Online Library
Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …

Controlled/living radical polymerization: Features, developments, and perspectives

WA Braunecker, K Matyjaszewski - Progress in polymer science, 2007 - Elsevier
Recent mechanistic developments in the field of controlled/living radical polymerization
(CRP) are reviewed. Particular emphasis is placed on structure–reactivity correlations and …

Kinetics of atom transfer radical polymerization

P Krys, K Matyjaszewski - European Polymer Journal, 2017 - Elsevier
This review encompasses the fundamentals of kinetics of atom transfer radical
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …

Transition metal-catalyzed living radical polymerization: toward perfection in catalysis and precision polymer synthesis

M Ouchi, T Terashima, M Sawamoto - Chemical Reviews, 2009 - ACS Publications
Precision control of radical polymerization, or living radical polymerization, has been among
the most important and long-waited subjects in polymer chemistry and macromolecular …

“Green” atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials

NV Tsarevsky, K Matyjaszewski - Chemical reviews, 2007 - ACS Publications
Virtually every branch of science, technology, and art uses a plethora of polymeric materials.
These include not only “pure” linear, branched, or cross-linked (gels, rubbers, etc.) polymers …

Synthesis of functional polymers with controlled architecture by CRP of monomers in the presence of cross-linkers: From stars to gels

H Gao, K Matyjaszewski - Progress in Polymer Science, 2009 - Elsevier
Recent developments in the synthesis of functional polymers with controlled architecture
and site-specific functionality via applying controlled radical polymerization (CRP) …

Transition metal catalysts for controlled radical polymerization

F Di Lena, K Matyjaszewski - Progress in Polymer Science, 2010 - Elsevier
The discovery, in the mid 1990s, that certain cobalt, ruthenium and copper complexes could
effectively control the radical polymerization of a number of polar olefins, allowing for the …

50th Anniversary Perspective: Metal-Catalyzed Living Radical Polymerization: Discovery and Perspective

M Ouchi, M Sawamoto - Macromolecules, 2017 - ACS Publications
Development of living polymerizations via reversible activation of dormant species opened
the door to discovery of metal-catalyzed living radical polymerization that is now very useful …

Surface functionalization of biomaterials by radical polymerization

T Zhou, Y Zhu, X Li, X Liu, KWK Yeung, S Wu… - Progress in Materials …, 2016 - Elsevier
One effective strategy in the field of biomaterials is to develop biomimetic interfaces to
modulate the cell behavior and promote tissue regeneration and surface modification is the …

Organotellurium compounds as novel initiators for controlled/living radical polymerizations. Synthesis of functionalized polystyrenes and end-group modifications

S Yamago, K Iida, J Yoshida - Journal of the American Chemical …, 2002 - ACS Publications
Polymer-end mimetic organotellurium compounds initiate controlled/living radical
polymerization of styrene derivatives that allows accurate molecular weight control with …