A Different Story of π-delocalization the Distortivity of π-electrons and Its Chemical Manifestations

S Shaik, A Shurki, D Danovich, PC Hiberty - Chemical Reviews, 2001 - ACS Publications
The delocalized π-electronic component of benzene is unstable toward a localizing
distortion and is at the same time stabilized by resonance relative to a localized reference …

An energetic measure of aromaticity and antiaromaticity based on the Pauling–Wheland resonance energies

Y Mo, PR Schleyer - Chemistry–A European Journal, 2006 - Wiley Online Library
Various criteria based on geometric, energetic, magnetic, and electronic properties are
employed to delineate aromatic and antiaromatic systems. The recently proposed block …

Cycloproparenes

B Halton - Chemical reviews, 2003 - ACS Publications
The field of the cycloproparene chemistry can be aptly regarded as something of a
Cinderella area since the simple beginnings have led to a wealth of fascinating and fruitful …

[图书][B] Ion-radical organic chemistry: principles and applications

ZV Todres - 2008 - taylorfrancis.com
Consolidating knowledge from a number of disciplines, Ion-Radical Organic Chemistry:
Principles and Applications, Second Edition presents the recent changes that have occurred …

About the Antiaromaticity of Planar Cyclooctatetraene.

FG Klärner - Angewandte Chemie (International ed. in English), 2001 - europepmc.org
A negligible antiaromatic destabilization is found in planar D 4h 1, 3, 5, 7-cyclooctatetraene
with alternating bond lengths. The same is also true for the delocalized D 8h structure, which …

Toward improved catholyte materials for redox flow batteries: what controls chemical stability of persistent radical cations?

J Zhang, IA Shkrob, RS Assary, S Tung… - The Journal of …, 2017 - ACS Publications
Catholyte materials are used to store positive charge in energized fluids circulating through
redox flow batteries (RFBs) for electric grid and vehicle applications. Energy-rich radical …

Lithium-cation/π complexes of aromatic systems. The effect of increasing the number of fused rings

JF Gal, PC Maria, M Decouzon, O Mó… - Journal of the …, 2003 - ACS Publications
The gas-phase lithium cation basicities (LCBs) of naphthalene, azulene, anthracene, and
phenanthrene were measured by means of Fourier transform ion cyclotron resonance (FT …

Structural studies on the radical cations of benzene, naphthalene, biphenylene, and anthracene fully annelated with bicyclo [2.2. 2] octene frameworks

A Matsuura, T Nishinaga… - Journal of the American …, 2000 - ACS Publications
The cyclic voltammetry of benzene 1, naphthalene 2, biphenylene 3, and anthracene 4 fully
annelated with bicyclo [2.2. 2] octene showed that their cationic species have enhanced …

Enantioselective Construction of Modular and Asymmetric Baskets

MJ Gunther, RZ Pavlović, TJ Finnegan… - Angewandte …, 2021 - Wiley Online Library
The precise positioning of functional groups about the inner space of abiotic hosts is a
challenging task and of interest for developing more effective receptors and catalysts akin to …

Soluble cycloannulated tetroxa [8] circulane derivatives: synthesis, optical and electrochemical properties, and generation of their robust cation–radical salts

R Rathore, SH Abdelwahed - Tetrahedron letters, 2004 - Elsevier
Syntheses of soluble bicycloalkane-annulated tetraoxa [8] circulane derivatives via Lewis
acid-catalyzed tetramerization of readily available cycloannulated benzoquinons is …