The development of reliable water oxidation catalysts (WOCs) is essential for implementing
artificial photosynthesis on a large technological scale. WOC research has evolved into two …

The coordination chemistry of corrole is one of the most intriguing aspects of this contracted
porphyrinoid, for both theoretical and practical reasons. Corrole, in fact, shows a remarkable …

The oxygen evolution reaction (OER) is a key process that enables the storage of renewable
energies in the form of chemical fuels. Here, we describe a catalyst that exhibits turnover …

A major roadblock in realizing large-scale production of hydrogen via electrochemical water
splitting is the cost and inefficiency of current catalysts for the oxygen evolution reaction …

Conspectus For the past two decades, linear free energy scaling relationships and volcano
plots have seen frequent use as computational tools that aid in understanding and …

Despite decades of effort, no earth-abundant homogeneous catalysts have been discovered
that can selectively oxidize methane to methanol. We exploit active learning to …

Catalytic processes are crucially important for many practical chemical applications.
Heterogeneous catalysts are especially appealing because of their high stability and the …

Developing cheap and efficient electrocatalysts for water splitting is required for energy
conversion techniques. Many first-row transition metal complexes have been shown to be …

The oxygen evolution reaction (OER) limits the performance of proton‐exchange membrane
electrolyzers since substantial overpotentials of several hundred millivolts are required for …

It has been well-established that unfavorable scaling relationships between* OOH,* OH,
and* O are responsible for the high overpotentials associated with oxygen electrochemistry …