Emerging trends in the dynamics of polyelectrolyte complexes

SM Lalwani, CI Eneh, JL Lutkenhaus - Physical Chemistry Chemical …, 2020 - pubs.rsc.org
Polyelectrolyte complexes (PECs) are highly tunable materials that result from the phase
separation that occurs upon mixing oppositely charged polymers. Over the years, they have …

Surface dynamics of glasses

H Tian, Q Xu, H Zhang, RD Priestley, B Zuo - Applied Physics Reviews, 2022 - pubs.aip.org
Two challenging scientific disciplines, ie, the physics of glasses [Anderson, Science 267,
1615 (1995); Kennedy and Norman, Science 309, 75 (2005)] and interface chemistry …

Direct visualization and characterization of interfacially adsorbed polymer atop nanoparticles and within nanocomposites

K Randazzo, M Bartkiewicz, B Graczykowski… - …, 2021 - ACS Publications
Irreversible adsorption at polymer/substrate interfaces has been reported to influence glassy
properties in thin films. However, consideration has yet to be extended to the nanocomposite …

Free‐Standing 2D Nanoassemblies

Q Shi, W Cheng - Advanced Functional Materials, 2020 - Wiley Online Library
Free‐standing 2D nanoassemblies are ultrathin nanomembranes or nanosheets
constructed from constituent nanoscale building blocks including metal nanoparticles …

Reaching the ideal glass in polymer spheres: Thermodynamics and vibrational density of states

X Monnier, J Colmenero, M Wolf, D Cangialosi - Physical review letters, 2021 - APS
The existence of an ideal glass and the resolution to the Kauzmann paradox is a long-
standing open question in materials science. To address this problem, we exploit the ability …

Influence of Surfactant-Mediated Interparticle Contacts on the Mechanical Stability of Supraparticles

J Wang, E Kang, U Sultan, B Merle… - The Journal of …, 2021 - ACS Publications
Colloidal supraparticles are micron-scale spherical assemblies of uniform primary particles,
which exhibit emergent properties of a colloidal crystal, yet exist as a dispersible powder. A …

Shell architecture strongly influences the glass transition, surface mobility, and elasticity of polymer core-shell nanoparticles

E Kang, B Graczykowski, U Jonas, D Christie… - …, 2019 - ACS Publications
Despite the growing application of nanostructured polymeric materials, there still remains a
large gap in our understanding of polymer mechanics and thermal stability under …

Optical imaging of the molecular mobility of single polystyrene nanospheres

S Liu, M Lv, H Li, S Wang, C Feng… - Journal of the …, 2022 - ACS Publications
An ultrathin surface layer with extraordinary molecular mobility has been discovered and
intensively investigated on thin-film polymer materials for decades. However, because of the …

Quantization of acoustic modes in dumbbell nanoparticles

Z Wang, H Kim, M Secchi, M Montagna, EM Furst… - Physical Review Letters, 2022 - APS
The vibrational eigenmodes of dumbbell-shaped polystyrene nanoparticles are recorded by
Brillouin light spectroscopy (BLS), and the full experimental spectra are calculated …

Upconverting Nanoparticles in Aqueous Media: Not a Dead‐End Road. Avoiding Degradation by Using Hydrophobic Polymer Shells

D Mendez‐Gonzalez, V Torres Vera, I Zabala Gutierrez… - Small, 2022 - Wiley Online Library
The stunning optical properties of upconverting nanoparticles (UCNPs) have inspired
promising biomedical technologies. Nevertheless, their transfer to aqueous media is often …