Since the prediction of the existence of metallabenzenes in 1979, metallaaromatic chemistry
has developed rapidly, due to its importance in both experimental and theoretical fields …

The concept of aromaticity was initially introduced in chemistry to account for the stability,
reactivity, molecular structures, and other properties of many unsaturated organic …

The design of organometallic catalysts is crucial in the development of catalytic reactions.
Herein, we describe a heterometallic [Os-Cu] complex with the characteristics of bimetallics …

Metallaaromatics can be broadly defined as aromatic compounds in which one of the ring
atoms is a transition metal. The metallabenzenes are one important class of these …

Conspectus The concept of aromaticity is one of the most fundamental principles in
chemistry. It is generally accepted that planarity is a prerequisite for aromaticity, and typically …

Abstract The first 1, 4‐distibabenzene‐1, 4‐diide compound [(ADC) Sb] 2 (5) based on an
anionic dicarbene (ADC)(ADC= PhC {N (Dipp) C} 2, Dipp= 2, 6‐iPr2C6H3) is reported as a …

While the implication of the aromaticity concept has been dramatically expanded to date
since its emergence in 1865, the classical [4n+ 2]/4n-electron counting protocol still plays an …

The isolation of silicon analogues of phenyl anions such as (C6H5)− and (C6H4) 2–is
challenging owing to their extremely high reactivity associated with their silylene character …

Aromaticity, a highly stabilizing feature of molecules with delocalized electrons in closed
circuits, is generally restricted to 'Hückel'systems with 4 n+ 2 mobile electrons. Although the …

Transition metal-containing metallabenzenes and metallabenzynes are organometallic
compounds derived from formal replacement of a CH group or a C atom in benzene and …