The diverse functions of isocyanides in phosphorescent metal complexes

GD Sutton, ME Olumba, YH Nguyen, TS Teets - Dalton Transactions, 2021 - pubs.rsc.org
In this Perspective, we highlight many examples of photoluminescent metal complexes
supported by isocyanides, with an emphasis on recent developments including several from …

High triplet energy iridium (III) isocyanoborato complex for photochemical upconversion, photoredox and energy transfer catalysis

L Schmid, F Glaser, R Schaer… - Journal of the American …, 2022 - ACS Publications
Cyclometalated Ir (III) complexes are often chosen as catalysts for challenging photoredox
and triplet–triplet-energy-transfer (TTET) catalyzed reactions, and they are of interest for …

Homoleptic Ir (III) phosphors with 2-phenyl-1, 2, 4-triazol-3-ylidene chelates for efficient blue organic light-emitting diodes

C You, XQ Wang, X Zhou, Y Yuan, LS Liao… - … Applied Materials & …, 2021 - ACS Publications
In this report, we synthesized two series of deep-blue-emitting homoleptic iridium (III)
phosphors bearing 1, 2, 4-triazol-3-ylidene and 5-(trifluoromethyl)-1, 2, 4-triazol-3-ylidene …

Luminescent Anionic Cyclometalated Organoplatinum (II) Complexes with Terminal and Bridging Cyanide Ligand: Structural and Photophysical Properties

M Sadeghian, D Gómez de Segura… - Inorganic …, 2023 - ACS Publications
We present the synthesis and characterization of two series of mononuclear heteroleptic
anionic cycloplatinated (II) complexes featuring terminal cyanide ligand Q+ [Pt (C^ N)(p …

Synthesis and Characterization of Blue Phosphorescent NHC-Ir (III) Complexes with Annulated Heterocyclic 1, 2, 4-Triazolophenanthridine Derivatives for Highly …

BS Yun, SY Kim, JH Kim, S Choi, S Lee… - ACS Applied …, 2022 - ACS Publications
Efficient tris-bidentate Ir (III) phosphorescent dopants were prepared using a series of 1, 2, 4-
triazolo [4, 3-f] phenanthridine (tzp) moieties modified with aryl substituents (phenyl, tolyl …

Phosphorescent Tris-cyclometalated Pt(IV) Complexes with Mesoionic N-Heterocyclic Carbene and 2-Arylpyridine Ligands

Á Vivancos, D Bautista, P González-Herrero - Inorganic Chemistry, 2022 - ACS Publications
The synthesis, structure, photophysical properties, and electrochemistry of the first series of
Pt (IV) tris-chelates bearing cyclometalated aryl-NHC ligands are reported. The complexes …

Manganese (I) Complex with Monodentate Arylisocyanide Ligands Shows Photodissociation Instead of Luminescence

S Ossinger, A Prescimone, D Haussinger… - Inorganic …, 2022 - ACS Publications
Recently reported manganese (I) complexes with chelating arylisocyanide ligands exhibit
luminescent metal-to-ligand charge-transfer (MLCT) excited states, similar to ruthenium (II) …

Combined Nucleophilic and Electrophilic Functionalization to Optimize Blue Phosphorescence in Cyclometalated Platinum Complexes

YH Nguyen, Y Wu, VQ Dang, C Jiang… - Journal of the American …, 2024 - ACS Publications
Ligand-based functionalization strategies have emerged as powerful approaches to tune
and optimize blue phosphorescence, which can involve nucleophilic addition to coordinated …

The position of NH2-subsituted group controlled the luminescent properties based on 4-amino-4H-1, 2, 4-triazole: Syntheses, crystal structures and Hirshfeld analyses

XK Chen, XM Chen, YR Xi, WC Sun, YT Wang… - Journal of Solid State …, 2022 - Elsevier
The tunable photoluminescent materials has drawn extensive attention in recent years. The
position of the substituents tuned the luminescent materials are one of attractive methods …

Mitochondria Localized Anticancer Iridium (III) Prodrugs for Targeted Delivery of Myeloid Cell Leukemia-1 (Mcl-1) Inhibitors and Cytotoxic Iridium (III) Complex

T Dixit, M Negi, V Venkatesh - Inorganic Chemistry, 2024 - ACS Publications
Myeloid cell leukemia-1 (Mcl-1) is an antiapoptotic oncoprotein overexpressed in several
malignancies and acts as one of the promising therapeutic targets for cancer. Even though …