This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

This review highlights the preparation of sodium sulfinates (RSO2Na) and their multifaceted
synthetic applications. Substantial progress has been made over the last decade in the …

Although α-chiral C (sp 3)–S bonds are of enormous importance in organic synthesis and
related areas, the transition-metal-catalysed enantioselective C (sp 3)–S bond construction …

Chiral sulfones are important structural motifs in organic synthesis because of their
widespread use in pharmaceutical chemistry. In particular, chiral allylic sulfones have drawn …

A highly enantio‐and regioselective hydrosulfonylation of 1, 3‐dienes with sulfonyl
hydrazides has been realized by using a palladium catalyst containing a monodentate chiral …

Functionalized cyclic organic carbonates and carbamates are frequently used in a number
of transition metal-catalyzed decarboxylative reactions for the construction of interesting …

A carbene-catalyzed sulfonylation reaction between enone aryl aldehydes and sulfonyl
chlorides is disclosed. The reaction effectively installs sulfone moieties in a highly …

Impressive progress has been made in the copper‐catalyzed asymmetric propargylic
substitution (APS) reaction, but its use in remote asymmetric yne‐allylic substitution remains …

The chiral allylic sulfonylated group is a unique structural motif embedded in a range of
natural products and pharmaceuticals. Notably, the synthesis of structurally diverse chiral …

Abstract The asymmetric synthesis of 2, 2‐difluorinated tetrahydrofurans was accomplished
via enantioselective formal [3+ 2] cycloaddition catalyzed by palladium. The asymmetric …