O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts

MM Montemore, MA Van Spronsen, RJ Madix… - Chemical …, 2017 - ACS Publications
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …

Surface chemistry of late transition metal oxides

JF Weaver - Chemical reviews, 2013 - ACS Publications
The surface chemistry of late transition metal oxides is scientifically interesting and can play
a central role in commercial applications of heterogeneous catalysis. The late transition …

Observing the oxidation of platinum

MA Van Spronsen, JWM Frenken, IMN Groot - Nature communications, 2017 - nature.com
Despite its importance in oxidation catalysis, the active phase of Pt remains uncertain, even
for the Pt (111) single-crystal surface. Here, using a ReactorSTM, the catalytically relevant …

Highly active surfaces for CO oxidation on Rh, Pd, and Pt

MS Chen, Y Cai, Z Yan, KK Gath, S Axnanda… - Surface Science, 2007 - Elsevier
Studies show that the rate of CO oxidation on Pt-group metals at temperatures between 450
and 600K and pressures between 1 and 300Torr increases markedly with an increase in the …

The influence of Pt oxide formation and Pt dispersion on the reactions NO2⇔ NO+ 1/2 O2 over Pt/Al2O3 and Pt/BaO/Al2O3

L Olsson, E Fridell - Journal of Catalysis, 2002 - Elsevier
Flow reactor experiments and XPS measurements were used to investigate the observed
decrease in activity of Pt/Al2O3 and Pt/BaO/Al2O3 catalysts during reaction conditions. The …

Two-dimensional crystalline platinum oxide

J Cai, L Wei, J Liu, C Xue, Z Chen, Y Hu, Y Zang… - Nature Materials, 2024 - nature.com
Platinum (Pt) oxides are vital catalysts in numerous reactions, but research indicates that
they decompose at high temperatures, limiting their use in high-temperature applications. In …

Oxidation of a polycrystalline silver foil by reaction with ozone

GIN Waterhouse, GA Bowmaker, JB Metson - Applied Surface Science, 2001 - Elsevier
The surface oxidation of a polycrystalline silver foil by reaction with ozone (5mol% O3 in O2)
at 300K and ambient pressure was investigated. The morphology, microstructure and …

Formation and thermal stability of platinum oxides on size-selected platinum nanoparticles: support effects

LK Ono, B Yuan, H Heinrich… - The Journal of Physical …, 2010 - ACS Publications
This article presents a systematic study of the formation and thermal stability of Pt oxide
species on size-selected Pt nanoparticles (NPs) supported on SiO2, ZrO2, and TiO2 thin …

XPS Study of Stability and Reactivity of Oxidized Pt Nanoparticles Supported on TiO2

EI Vovk, AV Kalinkin, MY Smirnov… - The Journal of …, 2017 - ACS Publications
The method of X-ray photoelectron spectroscopy was used to study the interaction of the
model Pt/TiO2 catalysts with NO2 and the following reduction of the oxidized Pt …

Accurate coverage-dependence incorporated into first-principles kinetic models: Catalytic NO oxidation on Pt (1 1 1)

C Wu, DJ Schmidt, C Wolverton, WF Schneider - Journal of Catalysis, 2012 - Elsevier
The coverage of surface adsorbates influences both the number and types of sites available
for catalytic reactions at a heterogeneous surface, but accounting for adsorbate–adsorbate …