A cyclic alkyl (amino) carbene (CAAC)-stabilized 1, 4-diborabenzene (DBB, 1) reacts with
the group 10 precursor [Ni (CO) 4] to yield the DBB pogo-stick complex [(η6-DBB) Ni …

Metal–ligand cooperativity in homogeneous catalysis is emerging as a powerful tool for the
design of efficient transition-metal catalysts. This perspective highlights recent advances in …

Incorporating palladium in the first coordination sphere of acetato‐bridged lanthanoid
complexes,[Pd2Ln2 (H2O) 2 (AcO) 10]⋅ 2 AcOH (Ln= Gd (1), Y (2), Gd0. 4Y1. 6 (3), Eu (4)) …

In situ X-ray absorption spectroscopy (XAS) investigations have been performed to provide
insights into the reaction mechanism of a palladium (II) catalyzed undirected C–H …

We employ a metal‐metal salt metathesis strategy to access low‐valent tantalum‐copper
heterometallic architectures (Ta− μ2‐H2− Cu and Ta− μ3‐H2− Cu3) that emulate structural …

In an effort to generate triple-decker complexes comprising a {PdCl2} moiety in the middle
deck, we have explored the reactivity of [(Cp* M) 2 {μ-B2H2E2}], 1–4 (1: M= Co, E= S; 2: M …

Flexible ligands that can adapt their donor strength have enabled unique reactivity in a wide
range of inorganic complexes. Most examples are composed of flexible multi-dentate …

The synthesis and reactivity of a new trimetallic complex Ti (NP) 4Ni2 (NP= 2-
diphenylphosphinopyrrolide)(3) is reported. Single-crystal X-ray diffraction and X-ray …

This work reports on the redox and acid–base properties of binuclear complexes of nickel
from 1, 4‐terphenyldithiophenol ligands. The results provide insight into the cooperative …

Abstract Palladium-catalyzed, hydroxy-group-directed C–H arylation of [1, 1′-biphenyl]-2-
ols with chloroarenes was performed. The reaction showed a broad substrate scope and …