Synthesis of a BC-Dihydrodipyrrin Building Block of Bacteriochlorophyll a
KC Nguyen, JS Lindsey - The Journal of Organic Chemistry, 2023 - ACS Publications
A strategy for the synthesis of bacteriochlorophyll a relies on joining AD and BC halves that
contain the requisite stereochemical configurations of the target macrocycle. The BC half (1) …
contain the requisite stereochemical configurations of the target macrocycle. The BC half (1) …
Synthesis of model southern rim structures of photosynthetic tetrapyrroles and phyllobilins
The photosynthetic tetrapyrroles and their catabolic products (phyllobilins) share similar
structural features in the southern rim encompassing rings C–E with variation in the degree …
structural features in the southern rim encompassing rings C–E with variation in the degree …
Synthesis of a model phyllobilin bearing an optical marker
Phyllobilins, derived from the breakdown of chlorophyll in plants, are acyclic tetrapyrroles
that bear the signature ring E of the parent macrocycle. Few synthetic studies have …
that bear the signature ring E of the parent macrocycle. Few synthetic studies have …
[引用][C] Bacteriochlorin syntheses-Status, problems, and exploration
Bacteriochlorins–Nature's near-infrared (NIR) chromophores–are distinguished by an
intense (𝜀∼; 105 M− 1 cm− 1) long-wavelength absorption band in the∼; 700–1000 nm …
intense (𝜀∼; 105 M− 1 cm− 1) long-wavelength absorption band in the∼; 700–1000 nm …