Brønsted–Lowry acid strength of metal hydride and dihydrogen complexes

RH Morris - Chemical Reviews, 2016 - ACS Publications
Transition metal hydride complexes are usually amphoteric, not only acting as hydride
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …

Control of Catalyst Isomers Using an N-Phenyl-Substituted RN(CH2CH2PiPr2)2 Pincer Ligand in CO2 Hydrogenation and Formic Acid Dehydrogenation

JB Curley, C Hert, WH Bernskoetter, N Hazari… - Inorganic …, 2021 - ACS Publications
A novel pincer ligand, iPrPNPhP [PhN (CH2CH2PiPr2) 2], which is an analogue of the
versatile MACHO ligand, iPrPNHP [HN (CH2CH2PiPr2) 2], was synthesized and …

Iron, Cobalt, and Nickel Complexes Supported by a iPrPNPhP Pincer Ligand

JB Curley, TM Townsend, WH Bernskoetter… - …, 2022 - ACS Publications
The synthesis of a series of Fe, Co, and Ni complexes supported by an iPrPNPhP
(iPrPNPhP= PhN (CH2CH2PiPr2) 2) pincer ligand is described. These complexes were …

Iron Catalysts Supported by a PNP Ligand with an Additional Hemilabile Donor for CO2 Hydrogenation

JC Wedal, KB Virtue, WH Bernskoetter, N Hazari… - ACS …, 2024 - ACS Publications
Iron complexes supported by pincer ligands of the type R'N (CH2CH2PR2) 2 (RPNR'P) are
highly active catalysts for a range of hydrogenation and dehydrogenation reactions but are …

Structure–function relationship in ester hydrogenation catalyzed by ruthenium CNN-pincer complexes

L Le, J Liu, T He, D Kim, EJ Lindley… - …, 2018 - ACS Publications
A series of six pincer–ruthenium complexes has been synthesized and applied in the
catalytic hydrogenation of esters. The ruthenium complexes have the formula Ru (pincer) …

Approaches to Sigma Complexes via Displacement of Agostic Interactions: An Experimental and Theoretical Investigation

A Ramaraj, KHK Reddy, H Keil, R Herbst-Irmer… - …, 2017 - ACS Publications
A series of coordinatively unsaturated, 16-electron, cationic ruthenium complexes bearing
PNP pincer ligands of the type [RuH (L)(PNRP)]+(L= PPh3, R= PhCH2 (3), Ph (4); L= CO …

Ruthenium Complexes Based on C2B9-nido-Carborane and Tridentate Phosphorus- and Nitrogen-Containing Ligands

AA Kal'tenberg, AD Bashilova, NV Somov… - Russian Journal of …, 2023 - Springer
Abstract Reaction of bis (2-(diphenylphosphino) ethyl) benzylamine (PNP) and bis (2-
methylpyridyl) benzylamine (NNN) with known closo-ruthenacarborane [3-H-3-Cl-3, 3 …

Комплексы рутения на основе C 2 B 9-нидо-карборана и тридентатных фосфор-и азотсодержащих лигандов

АА Кальтенберг, АД Башилова… - Žurnal …, 2023 - journals.rcsi.science
Взаимодействие бис (2-(дифенилфосфино) этил) бензиламина (PNP) и бис (2-
метилпиридил) бензиламина (NNN) с известным клозо-рутенакарбораном [3-H-3-Cl-3 …