A novel Salamo-Salen-Salamo hybrid Mg (II) complex fluorescent chemosensor for highly effective monitoring H2PO4ˉ in Zebrafish and plants

YT La, YJ Yan, X Li, Y Zhang, YX Sun… - Journal of Molecular …, 2024 - Elsevier
Abstract A novel Salamo-Salen-Salamo hybrid Mg (II) complex (sensor MT) was well-
designed and synthesized for selective sensing of H 2 PO 4 ˉ ions through ICT and CHEF …

Transition-Metal and Photocatalyst-Free, Redox-Neutral Heteroarylation of C(sp3)–H Bonds

K Almagambetova, K Murugesan, M Rueping - ACS Catalysis, 2024 - ACS Publications
Developing a transition-metal-free system for functionalizing the C (sp3)–H bond has posed
a long-standing challenge in synthetic organic chemistry and is of significance in drug …

Photocatalytic regioselective C–H bond functionalizations in arenes

J Hu, S Pradhan, S Waiba, S Das - Chemical Science, 2024 - pubs.rsc.org
The direct functionalization of C–H bonds has revolutionized the field of synthetic organic
chemistry by enabling efficient and atom-economical modification of arenes by avoiding …

Iron-Catalyzed Primary Amination of C(sp3)–H Bonds

Y Liu, Y Chen, YJ Zhao, GQ Zhang… - Journal of the …, 2024 - ACS Publications
Primary amines are privileged molecules in drug development. Yet, there is a noticeable
scarcity of methods for directly introducing a primary amine group into the ubiquitous C (sp3) …

Reactivity of Superbasic Carbanions Generated via Reductive Radical‐Polar Crossover in the Context of Photoredox Catalysis

S Grotjahn, C Graf, J Zelenka… - Angewandte Chemie …, 2024 - Wiley Online Library
Photocatalytic reactions involving a reductive radical‐polar crossover (RRPCO) generate
intermediates with carbanionic reactivity. Many of these proposed intermediates resemble …

Iodine (III)-mediated photochemical C–H azolation

X Han, W Yue, Z Wang, H Xu, M Yang, J Zhu - Organic Letters, 2024 - ACS Publications
A systematic radical polarity analysis framework is formulated herein for the projection of
radical reactivity patterns. An iodine (III)-mediated photochemical C–H azolation reaction …

Graphitic carbon nitride as a photocatalyst for decarboxylative C (sp2)–C (sp3) couplings via nickel catalysis

F Lukas, MT Findlay, M Fillols, J Templ… - Angewandte Chemie …, 2024 - Wiley Online Library
The development of robust and reliable methods for the construction of C (sp2)–C (sp3)
bonds is vital for accessing an increased array of structurally diverse scaffolds in drug …

Design of two different functional molecular logic devices based on hybrid fluorescence resonanceelectron exchange energy transfer

J Zhang, L Cai, Y Mo, X Hu, H Lin - Chemical Physics, 2023 - Elsevier
Faster and more convenient construction of different functional multi-input–multi-output
molecular logic devices has become a current research hotspot. In this study, a complex was …

Al(OTf)3-Catalyzed Regioselective N2–Arylation of Tetrazoles with Diazo Compounds

S Zhou, C Li, J Zeng, J Lv, J Liao, H Wang… - The Journal of …, 2024 - ACS Publications
Regioselective methods to access alkylated tetrazoles still remain a challenging goal.
Herein, we describe a novel regioselective protocol for N2-arylation of tetrazoles with diazo …

Photomediated controllable alkylation/nitrosoalkylation of N-heteroaromatics via nucleohomolytic substitution of alkylboronic esters with N-nitrosamines

JW Sang, Y Zhang, D Xia, Z Hu, J Wang… - Organic Chemistry …, 2025 - pubs.rsc.org
The development of sustainable late-stage functionalization (LSF) methods has become a
focal point of research in the field of organic synthesis. Boronic acids and their derivatives …