Catalytic oxidation of methane to oxygenated products: recent advancements and prospects for electrocatalytic and photocatalytic conversion at low temperatures

MSA Sher Shah, C Oh, H Park, YJ Hwang… - Advanced …, 2020 - Wiley Online Library
Methane is an important fossil fuel and widely available on the earth's crust. It is a
greenhouse gas that has more severe warming effect than CO2. Unfortunately, the emission …

A review on electrocatalytic oxidation of methane to oxygenates

AHB Mostaghimi, TA Al-Attas, MG Kibria… - Journal of Materials …, 2020 - pubs.rsc.org
Methane, the main component in natural gas, is widely utilized for energy consumption and
production of important chemicals. However, existing industrial processes for (direct or …

Electro-assisted methane oxidation to formic acid via in-situ cathodically generated H2O2 under ambient conditions

J Kim, JH Kim, C Oh, H Yun, E Lee, HS Oh… - Nature …, 2023 - nature.com
Direct partial oxidation of methane to liquid oxygenates has been regarded as a potential
route to valorize methane. However, CH4 activation usually requires a high temperature and …

Fundamental Limitation in Electrochemical Methane Oxidation to Alcohol: A Review and Theoretical Perspective on Overcoming It

MRA Kishore, S Lee, JS Yoo - Advanced Science, 2023 - Wiley Online Library
The direct conversion of gaseous methane to energy‐dense liquid derivatives such as
methanol and ethanol is of profound importance for the more efficient utilization of natural …

Heading to distributed electrocatalytic conversion of small abundant molecules into fuels, chemicals, and fertilizers

AJ Martín, J Pérez-Ramírez - Joule, 2019 - cell.com
The centralized production of fuels, chemicals, and fertilizers by thermocatalytic processes
sustained by fossil resources is a pillar of modern societies. Electrocatalytic transformations …

Electrocatalytic methane oxidation greatly promoted by chlorine intermediates

Q Wang, T Li, C Yang, M Chen, A Guan… - Angewandte Chemie …, 2021 - Wiley Online Library
Renewable energy‐powered methane (CH4) conversion at ambient conditions is an
attractive but highly challenging field. Due to the highly inert character of CH4, the selective …

A perspective on the electrochemical oxidation of methane to methanol in membrane electrode assemblies

JC Fornaciari, D Primc, K Kawashima… - ACS Energy …, 2020 - ACS Publications
Direct conversion of methane to methanol has been a long-sought objective. Partial
oxidation by thermal catalysis is possible but suffers from a rapid loss in methanol selectivity …

Selective electrocatalytic conversion of methane to fuels and chemicals

S Xie, S Lin, Q Zhang, Z Tian, Y Wang - Journal of energy chemistry, 2018 - Elsevier
The increase in natural gas reserves makes methane a significant hydrocarbon feedstock.
However, the direct catalytic conversion of methane into liquid fuels and useful chemicals …

[HTML][HTML] Strategies toward the sustainable electrochemical oxidation of methane to methanol

JA Arminio-Ravelo, M Escudero-Escribano - Current Opinion in Green and …, 2021 - Elsevier
The direct conversion of methane to methanol is very promising to achieve a decarbonized
future, but remains a great challenge. The electrochemical activation and partial oxidation of …

Chloride-Promoted High-Rate Ambient Electrooxidation of Methane to Methanol on Patterned Cu–Ti Bimetallic Oxides

A Prajapati, R Sartape, NC Kani, JA Gauthier… - ACS …, 2022 - ACS Publications
The selective electrochemical methane oxidation reaction (MOR) has been challenging due
to higher CH4 activation barriers and lower solubility at ambient conditions. Here, we …