Two-component polymeric materials of fullerenes and the transition metal complexes: A bridge between metal–organic frameworks and conducting polymers

AL Balch, K Winkler - Chemical reviews, 2016 - ACS Publications
In this review, we examined the interactions of metal complexes and metal surfaces with
fullerenes. That information has been related to the formation of redox-active materials …

Synthesis and Characterization of a Lithium-Doped Fullerane (Lix-C60-Hy) for Reversible Hydrogen Storage

JA Teprovich Jr, MS Wellons, R Lascola, SJ Hwang… - Nano …, 2012 - ACS Publications
Herein, we present a lithium-doped fullerane (Li x-C60-H y) that is capable of reversibly
storing hydrogen through chemisorption at elevated temperatures and pressures. This …

Nanoconfined LiBH4 and Enhanced Mobility of Liand BH4 Studied by Solid-State NMR

MHW Verkuijlen, P Ngene, DW de Kort… - The Journal of …, 2012 - ACS Publications
The structural and dynamical properties of LiBH4 confined in porous carbon and ordered
porous silica are studied using 1H, 7Li, and 11B solid-state NMR. The 11B and 7Li NMR …

Bi-functional Li 2 B 12 H 12 for energy storage and conversion applications: solid-state electrolyte and luminescent down-conversion dye

JA Teprovich, H Colón-Mercado… - Journal of Materials …, 2015 - pubs.rsc.org
Our investigation of the chemical and physical properties of the alkali-metal dodecahydro-
closo-dodecaborate, Li2B12H12, determined that it is a bi-functional material that can be …

Rapid Li ion dynamics in the interfacial regions of nanocrystalline solids

S Breuer, M Uitz, HMR Wilkening - The Journal of Physical …, 2018 - ACS Publications
Diffusive processes are ubiquitous in nature. In solid state physics, metallurgy and materials
science the diffusivity of ions govern the functionality of many devices such as sensors or …

Reversible Hydrogen Storage in a LiBH4–C60 Nanocomposite

PA Ward, JA Teprovich Jr, B Peters… - The Journal of …, 2013 - ACS Publications
Reversible hydrogen storage in a LiBH4: C60 nanocomposite (70: 30 wt%) synthesized by
solvent-assisted mixing has been demonstrated. During the solvent-assisted mixing and …

Evaluation of the physi-and chemisorption of hydrogen in alkali (Na, Li) doped fullerenes

PA Ward, JA Teprovich Jr, RN Compton… - international journal of …, 2015 - Elsevier
In this study, alkali doped fullerenes synthesized by two different solvent assisted mixing
techniques are compared for their hydrogen uptake activity. In particular, we investigated the …

Experimental and Theoretical Analysis of Fast Lithium Ionic Conduction in a LiBH4–C60 Nanocomposite

JA Teprovich Jr, HR Colón-Mercado… - The Journal of …, 2014 - ACS Publications
We have developed a LiBH4–C60 nanocomposite that displays fast lithium ionic conduction
in the solid state. The material is a homogeneous nanocomposite that contains both LiBH4 …

In Situ NMR Study on the Interaction between LiBH4–Ca(BH4)2 and Mesoporous Scaffolds

HS Lee, SJ Hwang, HK Kim, YS Lee… - The Journal of …, 2012 - ACS Publications
We discuss the use of nuclear magnetic resonance (NMR) spectroscopy to investigate the
physical state of the eutectic composition of LiBH4–Ca (BH4) 2 (LC) infiltrated into …

Synergistic effect of nanoionic destabilization and partial dehydrogenation for enhanced ionic conductivity in MBH4-C60 (M = Li+, Na+) nanocomposites

JA Santos, P Simon, AR Bernot, C Babasi… - Journal of Solid State …, 2021 - Springer
In this work, we evaluate the electrochemical properties of MBH 4-C 60 (M= Li+, Na+)
nanocomposites for potential use as a solid-state electrolyte in alkali-ion batteries. The …