Electrochemical methods for synthesis and in situ generation of organometallic compounds

ZN Gafurov, AO Kantyukov, AA Kagilev… - Coordination Chemistry …, 2021 - Elsevier
The electrochemical methods have a huge synthetic potential in both academia and
industry. However, the implementation of electrochemistry for the synthesis of …

Asymmetric-waveform alternating current-promoted silver catalysis for C–H phosphorylation

L Zeng, Y Jiao, W Yan, Y Wu, S Wang, P Wang… - Nature …, 2023 - nature.com
Preventing metal deposition by cathodic reduction is a formidable challenge during
transition-metal-catalysed electrosynthesis under direct current (dc) electrolysis conditions …

Review of electrochemical transition‐metal‐catalyzed C− H functionalization reactions

S Changmai, S Sultana, AK Saikia - ChemistrySelect, 2023 - Wiley Online Library
The combination of organometallic C− H activation and electro‐catalysis has emerged as a
potent synthetic technique for various molecular scaffolds since it avoids the use of harmful …

Electrochemical-Promoted Nickel-Catalyzed Reductive Allylation of Aryl Halides

W Chen, S Ni, Y Wang, Y Pan - Organic Letters, 2022 - ACS Publications
Compared with conventional reductive coupling, reductive coupling under electrochemical
conditions without external reductants is greener, milder, and more efficient and is of …

Efficient and regioselective synthesis of ortho-diiodinated homobenzylic alcohol derivatives: in silico evaluation as potential anticancer IDO/TDO inhibitors

RM Al-Zoubi, WK Al-Jammal, M Shkoor… - Organic & …, 2024 - pubs.rsc.org
A simple and direct synthesis of 2, 6-diiodophenylethanol building blocks through highly
regioselective metalation (MIE)/oxirane SN2-type ring opening of 1, 2, 3-triiodobenzene is …

Electrooxidative Metal‐Free Cyclization of 4‐Arylaminocoumarins with DMF as C1‐Source

Y Weng, H Chen, N Li, L Yang… - Advanced Synthesis & …, 2021 - Wiley Online Library
An environmentally‐benign electrochemical approach for the construction of quinoline
derivatives employing N, N‐dimethylformamide (DMF) as the methine source has been …

Electroreductive Cross‐Electrophile Coupling of Aromatic Carbonyl Compounds and Alkyl Bromides

RX Li, XW Wang, Y Chen, XY He… - … Synthesis & Catalysis, 2024 - Wiley Online Library
Classical methods for the synthesis of tertiary alcohols mainly rely on the nucleophilic
addition of organometallic reagents to carbonyl compounds. Here, we disclose a strategy for …

Augmentation of Pd-catalysed oxidative C–H/C–H carbonylation through alternating current electrosynthesis

H Li, J Peng, L Zeng, L Zhou, M Shabbir, F Xiao… - Green …, 2024 - pubs.rsc.org
In light of the burgeoning biological applications associated with xanthones, the
development of highly efficient synthetic methodologies for their production has emerged as …

Unleashing the potentiality of metals: synergistic catalysis with light and electricity

Z Shen, JL Tu, B Huang - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
The integration of transition metals as catalysts has opened new avenues for organic
synthesis, including the activation and formation of diverse bonds. The combination of metal …

[HTML][HTML] C–C and C–N bond formation in electro-oxidation reactions of aromatic compounds

A Kononov, S Strekalova, E Kobeleva… - Current Research in …, 2024 - Elsevier
Abstract Atom-economical, eco-efficient, metal-and chemical oxidant-free formation of C–C
and C–N bond from C (sp 2)− H and C (sp 3)− H of arenes toward the direct synthesis of …