Catalysis by clusters with precise numbers of atoms

EC Tyo, S Vajda - Nature nanotechnology, 2015 - nature.com
Clusters that contain only a small number of atoms can exhibit unique and often unexpected
properties. The clusters are of particular interest in catalysis because they can act as …

Metallic clusters: theoretical background, properties and synthesis in microemulsions

D Buceta, Y Piñeiro, C Vázquez-Vázquez, J Rivas… - Catalysts, 2014 - mdpi.com
Reducing the size from the bulk material to nanoparticles produces a scaling behavior in
physical properties in the later ones, due to the large surface-to-volume fraction. By further …

Electrochemical synthesis of very stable photoluminescent copper clusters

N Vilar-Vidal, MC Blanco… - The Journal of …, 2010 - ACS Publications
Small fluorescent atomic copper clusters, stabilized by tetrabutylammonium nitrate, have
been synthesized by a simple electrochemical technique. These small clusters (Cu N, N<≈ …

Perspective: Size selected clusters for catalysis and electrochemistry

A Halder, LA Curtiss, A Fortunelli… - The Journal of Chemical …, 2018 - pubs.aip.org
Size-selected clusters containing a handful of atoms may possess noble catalytic properties
different from nano-sized or bulk catalysts. Size-and composition-selected clusters can also …

Silver-doped titania modified carbon electrode for electrochemical studies of furantril

DB Shikandar, NP Shetti, RM Kulkarni… - ECS Journal of Solid …, 2018 - iopscience.iop.org
An electrochemical method for the determination of an antrallinic acid derivative based on
nanoparticles modified electrode was studied through cyclic and differential pulse …

Silver nanoparticles supported on TiO2 nanotubes as active catalysts for ethanol oxidation

YQ Liang, ZD Cui, SL Zhu, Y Liu, XJ Yang - Journal of Catalysis, 2011 - Elsevier
Silver (Ag) nanoparticles were successfully assembled in self-organized TiO2 nanotubes by
the polyol process. Scanning electron microscopy, transmission electron microscopy, X-ray …

Size dependent catalytic activity of reusable subnanometer copper (0) clusters

N Vilar-Vidal, J Rivas, MA Lopez-Quintela - ACS Catalysis, 2012 - ACS Publications
The catalytic reduction of methylene blue (MB) to leucomethylene blue (LMB) by hydrazine
in the presence of size-selected copper clusters (CuCLs, Cu N, N= number of atoms, 2≤ …

An Interpenetrating Architecture Based on the Wells–Dawson Polyoxometalate and AgI···AgI Interactions

P Zhang, J Peng, H Pang, J Sha, M Zhu… - Crystal growth & …, 2011 - ACS Publications
A new compound based on the Wells–Dawson polyoxometalate, Ag7 (bbi) 5
(OH)(P2W18O62)(bbi= 1, 1′-(1, 4-butanediyl) bis (imidazole))(1), has been hydrothermally …

Highly fluorescent few atoms silver nanoclusters with strong photocatalytic activity synthesized by ultrashort light pulses

JMJ Santillán, D Muñetón Arboleda, D Muraca… - Scientific reports, 2020 - nature.com
While there are conventional chemical synthesis methods to generate metal nanoclusters
(NCs), many of them are adversely affected by the unavoidable contamination of the …

Silver nanoparticles‐modified films versus biomedical device‐associated infections

H Cao, X Liu - Wiley Interdisciplinary Reviews: Nanomedicine …, 2010 - Wiley Online Library
A serious issue related to biomedical devices (BDs) is that of bacterial infections. BDs
colonized by bacteria may cause infection or mortality. To prevent such infections, an …