Sublimable spin‐crossover complexes: From spin‐state switching to molecular devices

KS Kumar, M Ruben - Angewandte Chemie International …, 2021 - Wiley Online Library
Spin‐crossover (SCO) active transition metal complexes are an important class of
switchable molecular materials due to their bistable spin‐state switching characteristics at or …

Guest‐Dependent Spin‐Transition Behavior of Porous Coordination Polymers

R Ohtani, S Hayami - Chemistry–A European Journal, 2017 - Wiley Online Library
The host–guest composites of Hofmann‐type iron (II) spin‐transition (ST) porous
coordination polymers incorporating guest molecules show guest‐dependent ST behavior in …

Triazole‐based one‐dimensional spin‐crossover coordination polymers

O Roubeau - Chemistry–A European Journal, 2012 - Wiley Online Library
One‐dimensional coordination FeII polymers constructed through triple N1, N2‐1, 2, 4‐
triazole bridges form a unique class of spin‐crossover materials, the synthetic versatility of …

A Two‐Dimensional Iron (II) Coordination Polymer with Synergetic Spin‐Crossover and Luminescent Properties

JY Ge, Z Chen, L Zhang, X Liang, J Su… - Angewandte …, 2019 - Wiley Online Library
Abstract A composite material,{[Fe (L)(TPPE) 0.5]⋅ 3 CH3OH} n, has been constructed by
integrating the spin‐crossover (SCO) subunit FeII {diethyl (E, E)‐2, 2′‐[1, 2‐phenyl‐bis …

First Step Towards a Devil's Staircase in Spin‐Crossover Materials

E Trzop, D Zhang, L Piñeiro‐Lopez… - Angewandte …, 2016 - Wiley Online Library
The unprecedented bimetallic 2D coordination polymer {Fe [(Hg (SCN) 3) 2](4, 4′‐bipy) 2}
n exhibits a thermal high‐spin (HS)↔ low‐spin (LS) staircase‐like conversion characterized …

Structural Insights into Hysteretic Spin‐Crossover in a Set of Iron(II)‐2,6‐bis(1H‐Pyrazol‐1‐yl)Pyridine) Complexes

N Suryadevara, A Mizuno, L Spieker… - … A European Journal, 2022 - Wiley Online Library
Bistable spin‐crossover (SCO) complexes that undergo abrupt and hysteretic (ΔT1/2) spin‐
state switching are desirable for molecule‐based switching and memory applications. In this …

Synthesis and Characterisation of a New Series of Bistable Iron (II) Spin‐Crossover 2D Metal–Organic Frameworks

V Martínez, AB Gaspar, MC Muñoz… - … A European Journal, 2009 - Wiley Online Library
Twelve coordination polymers with formula {Fe (3‐Xpy) 2 [MII (CN) 4]}(MII: Ni, Pd, Pt; X: F, Cl,
Br, I; py: pyridine) have been synthesised, and their crystal structures have been determined …

Cooperative spin transition in a mononuclear manganese (III) complex

PN Martinho, B Gildea, MM Harris, T Lemma… - Angewandte …, 2012 - Wiley Online Library
Spin-crossover (SCO) molecules are a class of compounds that show promise for
application in memory devices.[1] A hysteretic transition pathway is essential in promoting a …

A Trinuclear Defect‐Grid Iron (II) Spin Crossover Complex with a Large Hysteresis Loop that is Readily Silenced by Solvent Vapor

M Steinert, B Schneider, S Dechert… - Angewandte …, 2014 - Wiley Online Library
A new type of [2× 2] matrix‐like complexes with one vertex devoid of a metal ion has been
selectively synthesized. The defect‐grid triiron (II) complex exhibits a sharp and complete …

Halogen Substitution Effects on N2O Schiff Base Ligands in Unprecedented Abrupt FeII Spin Crossover Complexes

W Phonsri, DS Macedo, KR Vignesh… - … A European Journal, 2017 - Wiley Online Library
A family of halogen‐substituted Schiff base iron (II) complexes,[FeII (qsal‐X) 2],(qsal‐X= 5‐X‐
N‐(8‐quinolyl) salicylaldimines)) in which X= F (1), Cl (2), Br (3) or I (4) has been …