Structure: function relationships in molecular spin-crossover complexes

MA Halcrow - Chemical Society Reviews, 2011 - pubs.rsc.org
Spin-crossover compounds are becoming increasingly popular for device and sensor
applications, and in soft materials, that make use of their switchable colour, paramagnetism …

Thermo-, piezo-, photo-and chemo-switchable spin crossover iron (II)-metallocyanate based coordination polymers

MC Munoz, JA Real - Coordination Chemistry Reviews, 2011 - Elsevier
The design of coordination polymers (CPs) with switch and memory functions is an important
subject of current interest in the search for new advanced materials with potential …

Guest programmable multistep spin crossover in a porous 2-D Hofmann-type material

MJ Murphy, KA Zenere, F Ragon… - Journal of the …, 2017 - ACS Publications
The spin crossover (SCO) phenomenon defines an elegant class of switchable materials
that can show cooperative transitions when long-range elastic interactions are present. Such …

Hysteretic Three‐Step Spin Crossover in a Thermo‐and Photochromic 3D Pillared Hofmann‐type Metal–Organic Framework

NF Sciortino, KR Scherl‐Gruenwald, G Chastanet… - Angewandte …, 2012 - infona.pl
Multistabilität wird bei einem Metall‐organischen Gerüstmaterial beobachtet, das einen
einzigartigen dreistufigen Spin‐Crossover mit einer thermischen Hysterese von 20 K …

Hysteretic Four‐Step Spin Crossover within a Three‐Dimensional Porous Hofmann‐like Material

JE Clements, JR Price, SM Neville… - Angewandte …, 2016 - Wiley Online Library
Materials that display multiple stepped spin crossover (SCO) transitions with accompanying
hysteresis present the opportunity for ternary, quaternary, and quinary electronic switching …

Dicyanometallates as model extended frameworks

JA Hill, AL Thompson, AL Goodwin - Journal of the American …, 2016 - ACS Publications
We report the structures of eight new dicyanometallate frameworks containing molecular
extra-framework cations. These systems include a number of hybrid inorganic–organic …

Coexistence of luminescence and spin-crossover in 2D iron (II) Hofmann clathrates modulated through guest encapsulation

R Turo-Cortés, M Meneses-Sánchez… - Journal of Materials …, 2022 - pubs.rsc.org
The search for advanced multifunctional materials displaying two or more simultaneous and
correlated physicochemical properties represents a key step in developing further practical …

Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au)

VM Hiiuk, SI Shylin, DD Barakhtii, DM Korytko… - Inorganic …, 2022 - ACS Publications
Two 2D Hofmann-type complexes of the composition [Fe (Phpz) 2 {M (CN) 2} 2](where
Phpz= 2-phenylpyrazine; M= Ag, Au) have been synthesized, and their spin-crossover …

Multi‐Step Spin Crossover Accompanied by Symmetry Breaking in an FeIII Complex: Crystallographic Evidence and DFT Studies

ZY Li, JW Dai, Y Shiota, K Yoshizawa… - … A European Journal, 2013 - Wiley Online Library
Molecular bistability plays an important role in developing advanced materials for
applications such as molecularlevel sensors, switches, and memory. Therefore, molecular …

Spin crossover in FeII cyanometallic frameworks

OI Kucheriv, IO Fritsky, A Il'ya - Inorganica Chimica Acta, 2021 - Elsevier
Spin-crossover (SCO) compounds represent a huge class of switchable coordination
complexes that can change their electronic configurations under the influence of different …