Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Recent advances in transition-metal-catalyzed functionalization of unstrained carbon–carbon bonds

F Chen, T Wang, N Jiao - Chemical Reviews, 2014 - ACS Publications
The carbon− carbon bond is the most widespread and fundamental bond existing in organic
compounds. The reaction of this kind of bond is almost ubiquitous in live activities and …

From ketones to esters by a Cu-catalyzed highly selective C (CO)–C (alkyl) bond cleavage: aerobic oxidation and oxygenation with air

X Huang, X Li, M Zou, S Song, C Tang… - Journal of the …, 2014 - ACS Publications
The Cu-catalyzed aerobic oxidative esterification of simple ketones via C–C bond cleavage
has been developed. Varieties of common ketones, even inactive aryl long-chain alkyl …

Modulating the phases of iron carbide nanoparticles: from a perspective of interfering with the carbon penetration of Fe@ Fe 3 O 4 by selectively adsorbed halide ions

Z Yang, T Zhao, X Huang, X Chu, T Tang, Y Ju… - Chemical …, 2017 - pubs.rsc.org
Iron carbide nanoparticles (ICNPs) are considered to have great potential in new energy
conversion, nanomagnets and biomedical applications due to their intrinsically peculiar …

Unstrained Carbon Carbon Bond Cleavage

H Liu, M Feng, X Jiang - Chemistry–An Asian Journal, 2014 - Wiley Online Library
Abstract This Focus Review presents recent developments in the cleavage of C C bonds in
organic molecules. Significant progress in C C activation, including the development of a …

Biorelevant metals in sustainable metal catalysis—a survey

MS Holzwarth, B Plietker - ChemCatChem, 2013 - Wiley Online Library
A growing world population and increasing energy demands are without a doubt the most
important challenges for mankind within this century. Catalysis is a key technology in various …

One-pot room-temperature conversion of cyclohexane to adipic acid by ozone and UV light

KC Hwang, A Sagadevan - Science, 2014 - science.org
Nitric acid oxidation of cyclohexane accounts for~ 95% of the worldwide adipic acid
production and is also responsible for~ 5 to 8% of the annual worldwide anthropogenic …

Regioselective hydration of alkynes by iron (III) Lewis/Brønsted catalysis

JR Cabrero‐Antonino, A Leyva‐Pérez… - … –A European Journal, 2012 - Wiley Online Library
The triflimide iron (III) salt [Fe (NTf2) 3] promotes the direct hydration of terminal and internal
alkynes with very good Markovnikov regioselectivities and high yields. The enhanced …

Deacylative allylation: allylic alkylation via retro-Claisen activation

AJ Grenning, JA Tunge - Journal of the American Chemical …, 2011 - ACS Publications
A new method for allylic alkylation of a variety of relatively nonstabilized carbon
nucleophiles is described herein. In this process of “deacylative allylation”, the coupling …

Asymmetric Retro-Claisen Reaction Catalyzed by Chiral Aza-Bisoxazoline–Zn (II) Complex: Enantioselective Synthesis of α-Arylated Ketones

JH Liu, XJ Lv, YK Liu - Organic Letters, 2023 - ACS Publications
An asymmetric retro-Claisen reaction of α-monosubstituted β-diketones and quinones (or
quinone imine) has been developed under the catalysis of a chiral aza-bisoxazoline–Zn (II) …