[PDF][PDF] 13.2–The chemistry of metal transport and deposition by ore-forming hydrothermal fluids

TM Seward, AE Williams-Jones… - Treatise on …, 2014 - researchgate.net
Economically exploitable deposits of metallic minerals (ore deposits) form in the Earth's crust
through a variety of geologic processes. These involve extraction of metals at low …

An XAS study of molybdenum speciation in hydrothermal chloride solutions from 25–385 C and 600 bar

S Borg, W Liu, B Etschmann, Y Tian… - … et Cosmochimica Acta, 2012 - Elsevier
Molybdenum (VI) is expected to be the main form of Mo in hydrothermal fluids up to
magmatic hydrothermal conditions. We conducted an in situ X-ray absorption spectroscopic …

Molybdenum speciation in magmatic-hydrothermal fluids: Constraints from molybdenite solubility experiments and thermodynamic modeling

J Fang, A Audétat, D Dolejš - Geochimica et Cosmochimica Acta, 2025 - Elsevier
Magmatic-hydrothermal ore deposits are the world's major source of molybdenum (Mo), yet
the speciation of Mo in magmatic-hydrothermal fluids is still uncertain. We experimentally …

Solution structures and acidity constants of molybdic acid

X Liu, J Cheng, M Sprik, X Lu - The Journal of Physical Chemistry …, 2013 - ACS Publications
Experiment has not been able to discriminate between the oxo (MoO3·(H2O) 3) and
oxyhydroxide (MoO2 (OH) 2·(H2O) 2) forms of molybdic acid. Using first-principles molecular …

Zinc transport in hydrothermal fluids: On the roles of pressure and sulfur vs. chlorine complexing

B Etschmann, W Liu, R Mayanovic, Y Mei… - American …, 2019 - degruyter.com
We provide an experimental confirmation of the suggestion, based on thermodynamic
simulations and extrapolations (Zhong et al. 2015), that Zn is transported in the form of …

An investigation of the Fe and Mo oxidation states in Sr2Fe2− xMoxO6 (0.25⩽ x⩽ 1.0) double perovskites by X-ray absorption spectroscopy

JR Hayes, AP Grosvenor - Journal of alloys and compounds, 2012 - Elsevier
Sr2FeMoO6 double perovskite systems are widely studied because of their interesting and
technologically relevant physical properties. Sr2FeMoO6 is just a single composition in the …

Thermal reduction of molybdite and hematite in water and hydrogen peroxide-bearing solutions: Insights on redox conditions in Hydrothermal Diamond Anvil Cell …

G Solferino, AJ Anderson - Chemical Geology, 2012 - Elsevier
The oxygen fugacity in Hydrothermal Diamond Anvil Cell (HDAC) experiments was
determined by means of direct observation of the thermal reduction of molybdite or hematite …

Solubility of calcium molybdate in aqueous solutions at 573 K and thermodynamics of monomer hydrolysis of Mo (VI) at elevated temperatures

TP Dadze, GA Kashirtseva, MP Novikov… - Monatshefte für Chemie …, 2018 - Springer
This study presents new experimental results on solubility of synthetic crystalline calcium
molybdate, CaMoO 4 (cr), at 573 K and pressure~ 10 MPa in aqueous solutions of HCl (10 …

A hydrothermal apparatus for x-ray absorption spectroscopy of hydrothermal fluids at DESY

S Klemme, M Feldhaus, V Potapkin, M Wilke… - Review of Scientific …, 2021 - pubs.aip.org
We present a new autoclave that enables in situ characterization of hydrothermal fluids at
high pressures and high temperatures at synchrotron x-ray radiation sources. The autoclave …

Design of a continuous-flow reactor for in situ x-ray absorption spectroscopy of solids in supercritical fluids

M Dreher, E De Boni, M Nachtegaal… - Review of Scientific …, 2012 - pubs.aip.org
This paper presents the design and performance of a novel high-temperature and high-
pressure continuous-flow reactor, which allows for x-ray absorption spectroscopy or …