Phosphorus compounds bearing chirality on the P-center are usually qualified as P-
chirogenic or P-stereogenic. This chemical class concerns natural products, agrochemistry …

Stereoconvergent catalysis is an important subset of asymmetric synthesis that
encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic …

The first highly enantioselective catalytic synthesis of P-stereogenic secondary phosphine-
boranes was realized by the asymmetric addition of primary phosphine to electron-deficient …

The practical synthesis of P-stereogenic tertiary phosphines, which have wide applications
in asymmetric catalysis, materials, and pharmaceutical chemistry, represents a significant …

P‐stereogenic tert‐and sec‐phosphines have wide applications in asymmetric catalysis,
materials, and pharmaceutical chemistry, however, their practical synthesis still constitutes a …

The development of transition-metal-catalyzed methods for the synthesis of P-chiral
phosphine derivatives poses a considerable challenge. Herein, we present a direct Pd/Xiao …

A copper (I)-catalyzed asymmetric alkylation of HPAr1Ar2 with alkyl halides is uncovered,
which provides an array of P-stereogenic phosphines in generally high yield and …

The catalytic asymmetric synthesis of P‐chiral phosphorus compounds is an important way
to construct P‐chiral ligands. Herein, we report a new strategy that adopts the pyridinyl …

A general and mild nickel‐catalyzed enantioselective C (sp2)− P cross‐coupling for
synthesizing P‐stereogenic phosphine oxides has been developed. The asymmetric …

We present the enantioselective synthesis of P-stereogenic phosphinamides through Pd-
catalyzed desymmetric ortho C–H arylation of diarylphosphinamides with boronic esters …