Shifts in the ground-state vibrational fundamental frequencies of diatomic and small
polyatomic free radicals, molecular ions, and other short-lived molecules upon trapping in …

The synthesis of methyl mercaptan from COS and H 2 on K+ promoted MoS 2 supported on
silica is explored. The reaction proceeds via the disproportionation of COS to CO 2 and CS 2 …

Alkali metals are commonly used to promote heterogeneous catalysts. For instance, K can
enhance the MoS 2-catalyzed synthesis of methanethiol, an important industrial chemical …

A combination of matrix isolation technique and Fourier transform infrared spectroscopy has
been used to study the low-temperature photochemistry of isothiocyanic acid HNCS. Near …

The results of spectroscopic (mainly vibrational IR spectroscopy and EPR spectroscopy)
studies of radicals stabilized in solid inert-gas matrices are considered. Attention is focused …

Thioformic acid (TFA) is the sulfur analog of formic acid, the simplest organic acid. It has
three analogs, HCOSH, HCSOH, and HCSSH, each of them having two rotational isomeric …

The astrochemically relevant reactions of [H, C, N, S] isomers were studied both theoretically
and experimentally. The energetics and barriers of H-atom-addition and H-atom-abstraction …

Thioformaldehyde S-sulfide (Thiosulfine). - Abstract - Europe PMC Sign in | Create an account
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We study the reaction of atomic hydrogen with formic acid and characterize the radical
products using IR spectroscopy in a Kr matrix and quantum chemical calculations. The …

The radiation-induced transformations of isolated dimethyl disulphide molecules in a solid
argon matrix occurring under the action of X-rays at 4.5 K were studied by FTIR …