The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

The mainstream applications of visible‐light photoredox catalysis predominately involve
outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious …

In recent years, the integration of photocatalytic hydrogen atom transfer (HAT) with transition
metal catalysis has emerged as a formidable strategy for the construction of C (sp3)–carbon …

The intermediacy of alkoxy radicals in cerium-catalyzed C–H functionalization via H-atom
abstraction has been unambiguously confirmed. Catalytically relevant Ce (IV)–alkoxide …

Visible‐light photocatalysis is a rapidly developing and powerful strategy to initiate organic
transformations, as it closely adheres to the tenants of green and sustainable chemistry …

Conspectus In recent years, the development of light-driven reactions has contributed
numerous advances in synthetic organic chemistry. A particularly active research area …

The merger of transition metal catalysis and photocatalysis, termed metallaphotocatalysis,
has recently emerged as a versatile platform for the development of new, highly enabling …

With the recent soaring production of natural gas, the use of methane and other light
hydrocarbon feedstocks as starting materials in synthetic transformations is becoming …