Emerging materials and methods toward ammonia‐based energy storage and conversion

F Chang, W Gao, J Guo, P Chen - Advanced Materials, 2021 - Wiley Online Library
Efficient storage and conversion of renewable energies is of critical importance to the
sustainable growth of human society. With its distinguishing features of high hydrogen …

Advances in materials and applications of inorganic electrides

H Hosono, M Kitano - Chemical Reviews, 2021 - ACS Publications
Electrides are materials in which electrons serve as anions. Here, the concept of inorganic
electrides is extended in several respects: from ionic crystals to intermetallic compounds in …

Challenges and opportunities of Ru-based catalysts toward the synthesis and utilization of ammonia

H Fang, D Liu, Y Luo, Y Zhou, S Liang, X Wang… - ACS …, 2022 - ACS Publications
Ammonia is an important chemical for synthesized fertilizers traditionally and for a potential
energy vector increasingly. Industrial ammonia synthesis through the Haber–Bosch process …

Recent advances in heterogeneous catalysis for ammonia synthesis

VS Marakatti, EM Gaigneaux - ChemCatChem, 2020 - Wiley Online Library
Even after a century, ammonia (NH3) synthesis from nitrogen and hydrogen through Haber‐
Bosch process is still energy intensive. Even with recently introduced second generation Ru …

Metal‐Dependent Support Effects of Oxyhydride‐Supported Ru, Fe, Co Catalysts for Ammonia Synthesis

Y Tang, Y Kobayashi, N Masuda… - Advanced Energy …, 2018 - Wiley Online Library
Ammonia is an attractive energy carrier for the hydrogen economy, given its high hydrogen
density and ease of liquefaction. A titanate oxyhydride has recently been demonstrated that …

Hydride-based antiperovskites with soft anionic sublattices as fast alkali ionic conductors

S Gao, T Broux, S Fujii, C Tassel, K Yamamoto… - Nature …, 2021 - nature.com
Most solid-state materials are composed of p-block anions, only in recent years the
introduction of hydride anions (1s2) in oxides (eg, SrVO2H, BaTi (O, H) 3) has allowed the …

Splitting of hydrogen atoms into proton–electron pairs at BaO–Ru interfaces for promoting ammonia synthesis under mild conditions

Y Baik, M Kwen, K Lee, S Chi, S Lee… - Journal of the …, 2023 - ACS Publications
Ru catalysts promoted with alkali and alkaline earth have shown superior ammonia (NH3)
synthesis activities under mild conditions. Although these promoters play a vital role in …

Hidden chemical order in disordered Ba7Nb4MoO20 revealed by resonant X-ray diffraction and solid-state NMR

Y Yasui, M Tansho, K Fujii, Y Sakuda, A Goto… - Nature …, 2023 - nature.com
The chemical order and disorder of solids have a decisive influence on the material
properties. There are numerous materials exhibiting chemical order/disorder of atoms with …

Ruthenium Catalysts Promoted by Lanthanide Oxyhydrides with High Hydride‐Ion Mobility for Low‐Temperature Ammonia Synthesis

K Ooya, J Li, K Fukui, S Iimura, T Nakao… - Advanced Energy …, 2021 - Wiley Online Library
Lanthanum oxyhydrides were recently reported to be fast hydride ion conductors with the
highest conductivity at 100–400° C. Here, the relationship between the hydride‐ion …

Light-driven nitrogen fixation routes for green ammonia production

L Collado, AH Pizarro, M Barawi… - Chemical Society …, 2024 - pubs.rsc.org
The global goal for decarbonization of the energy sector and the chemical industry could
become a reality by a massive increase in renewable-based technologies. For this clean …