Analysis and control of acid sites in zeolites

A Palčić, V Valtchev - Applied Catalysis A: General, 2020 - Elsevier
The exceptional catalytic performance of zeolites is due to the presence of active sites in a
shape-selective environment, ie, in micropores with molecular dimensions. The present …

Tuning the aluminum distribution in zeolites to increase their performance in acid‐catalyzed reactions

J Dědeček, E Tabor, S Sklenak - ChemSusChem, 2019 - Wiley Online Library
The organization of Al atoms in the framework of Si‐rich zeolites is very important and
includes two classes:(i) the Al siting that determines which individual, crystallographically …

[HTML][HTML] Recent progress in the improvement of hydrothermal stability of zeolites

R Simancas, A Chokkalingam, SP Elangovan, Z Liu… - Chemical …, 2021 - pubs.rsc.org
Zeolites have been successfully employed in many catalytic reactions of industrial
relevance. The severe conditions required in some processes, where high temperatures are …

Cu/SSZ-13 and Cu/SAPO-34 catalysts for deNOx in diesel exhaust: Current status, challenges, and future perspectives

S Zhang, L Pang, Z Chen, S Ming, Y Dong, Q Liu… - Applied Catalysis A …, 2020 - Elsevier
Copper-exchanged SSZ-13 and SAPO-34 (Cu/CHA) zeolites catalysts have been
commercially utilized for selective catalytic reduction (SCR) of NO x by NH 3. Despite the …

Rare-earth ion exchanged Cu-SSZ-13 zeolite from organotemplate-free synthesis with enhanced hydrothermal stability in NH 3-SCR of NO x

Z Zhao, R Yu, C Shi, H Gies, FS Xiao… - Catalysis Science & …, 2019 - pubs.rsc.org
The relatively low hydrothermal stability of Al-rich Cu-SSZ-13 catalysts hinders their practical
application in ammonia selective catalytic reduction (NH3-SCR) reaction. Rare-earth ions …

Al organization in the SSZ-13 zeolite. Al distribution and extraframework sites of divalent cations

K Mlekodaj, J Dedecek, V Pashkova… - The Journal of …, 2018 - ACS Publications
SSZ-13 is a Si-rich (Si/Al> 5) small pore zeolite (chabazite topology) important for both acid
and redox catalysis. Using a sample with Si/Al= 12, a new procedure involving 27Al (3Q) …

Carbonylation of dimethyl ether to methyl acetate over SSZ-13

M Lusardi, TT Chen, M Kale, JH Kang, M Neurock… - ACS …, 2019 - ACS Publications
The small-pore zeolite with the chabazite framework topology, SSZ-13, is found to be an
active catalyst in the carbonylation of dimethyl ether to methyl acetate (MA). The production …

Recent experimental and theoretical studies on Al siting/acid site distribution in zeolite framework

S Wang, Y He, W Jiao, J Wang, W Fan - Current Opinion in Chemical …, 2019 - Elsevier
Highlights•Recent regulation and theoretical study on the Al siting/acid sties distribution in
zeolites were summarized.•The positions of Al in zeolite are simultaneously controlled by the …

Role of Al Distribution in CO2 Adsorption Capacity in RHO Zeolites

E Dib, EB Clatworthy, AA Paecklar… - The Journal of …, 2022 - ACS Publications
Tailoring the CO2 adsorption performance of high-aluminum-containing zeolites is typically
considered from the perspective of controlling the type and location of extra-framework …

Synthesis of high-performance and high-stability Pd (II)/NaY catalyst for CO direct selective conversion to dimethyl carbonate by rational design

HZ Tan, ZN Chen, ZN Xu, J Sun, ZQ Wang, R Si… - ACS …, 2019 - ACS Publications
Direct selective catalytic conversion of CO to C2+ oxygenates with high performance and
high stability is challenging. Generating dimethyl carbonate (DMC), a high added-value …