Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt (II) complexes with zero-field hidden single-molecule magnet behaviour: the …
A Landart-Gereka, MM Quesada-Moreno… - Inorganic Chemistry …, 2022 - pubs.rsc.org
The complexes [Co (L)] X· S (X= CoCl42−, S= CH3CN (1); X= ZnCl42−, S= CH3OH (2)),[Co
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
Structure-property correlation in stabilizing axial magnetic anisotropy in octahedral Co (II) complexes
Stabilizing an easy axis of magnetization in an octahedral Co (II) complex is an extremely
challenging task, which is evident from reports that more than 90% possess easy-plane …
challenging task, which is evident from reports that more than 90% possess easy-plane …
Structural, optical and magnetic properties of a new metal–organic Co II-based complex
W Jabeur, M Korb, M Hamdi, M Holub, D Princík… - RSC …, 2024 - pubs.rsc.org
A mononuclear cobalt (II) complex [C5H8N3] 2 [CoCl4 (C5H7N3) 2](I) was synthesized and
structurally characterized. Single crystal X-ray diffraction analysis indicates that …
structurally characterized. Single crystal X-ray diffraction analysis indicates that …
Switching of easy-axis to easy-plane anisotropy in cobalt (II) complexes
Y Wu, J Xi, T Xiao, J Ferrando-Soria… - Inorganic Chemistry …, 2021 - pubs.rsc.org
A tetranuclear cubane-type complex [Co4 (ntfa) 4 (CH3O) 4 (CH3OH) 4](1) with a {Co4O4}
core, and a mononuclear complex [Co (ntfa) 2 (CH3OH) 2](2) have been rationally obtained …
core, and a mononuclear complex [Co (ntfa) 2 (CH3OH) 2](2) have been rationally obtained …
Synthesis, structure, magnetic properties and thermal behaviour of Ba–M II (M II= Mn, Co, Cu, and Zn) allylmalonates
EN Zorina-Tikhonova, AK Matyukhina… - New Journal of …, 2022 - pubs.rsc.org
A series of Ba–MII complexes with allylmalonic acid anions (Amal)[BaMII (Amal) 2 (H2O) 3] n
(MII= Mn (1), Co (2), Cu (3), and Zn (4)) were synthesized by the reaction of the …
(MII= Mn (1), Co (2), Cu (3), and Zn (4)) were synthesized by the reaction of the …
Slow magnetic relaxation triggered by a structural phase transition in long-chain-alkylated cobalt (II) single-ion magnets
F Kobayashi, R Ohtani, M Nakamura… - Inorganic …, 2019 - ACS Publications
The behavior of single-ion magnets (SIMs) that reflects large distortions of their coordination
environments caused by the packing of long alkyl chains for two Co (II) complexes of the …
environments caused by the packing of long alkyl chains for two Co (II) complexes of the …
Purely spectroscopic determination of the spin Hamiltonian parameters in high-spin six-coordinated cobalt (II) complexes with large zero-field splitting
EY Misochko, AV Akimov, DV Korchagin… - Inorganic …, 2019 - ACS Publications
Accurate determination of the spin Hamiltonian parameters in transition-metal complexes
with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and …
with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and …
Field-induced single-ion magnet behaviour of a hexacoordinated Co (II) complex with easy-axis-type magnetic anisotropy
YP Tupolova, IN Shcherbakov, LD Popov… - Dalton …, 2019 - pubs.rsc.org
A coordination compound with the composition [CoLCl2]· H2O (L= bis-condensation product
of diacetyl and 2-hydrazinyl-4, 6-dimethylpyrimidine) was synthesized, in which the Co (II) …
of diacetyl and 2-hydrazinyl-4, 6-dimethylpyrimidine) was synthesized, in which the Co (II) …
Tuning magnetic anisotropy by the π-bonding features of the axial ligands and the electronic effects of gold (I) atoms in 2D {Co (L) 2 [Au (CN) 2] 2} n metal–organic …
MA Palacios, IF Díaz-Ortega, H Nojiri… - Inorganic Chemistry …, 2020 - pubs.rsc.org
The assembly of a Co (II) salt with two [Au (CN) 2]− anions and ancillary ligands L afforded
2D complexes of the general formula {Co (L) 2 [Au (CN) 2] 2} n (where L= DMSO (1), DMF …
2D complexes of the general formula {Co (L) 2 [Au (CN) 2] 2} n (where L= DMSO (1), DMF …
Magnetic relaxation in cobalt (ii)-based single-ion magnets influenced by distortion of the pseudotetrahedral [N 2 O 2] coordination environment
The synthesis, structure, and magnetic properties of two mononuclear cobalt (II) complexes
[Co (LSal, 2-Ph) 2](1) and [Co (LNph, 2-Ph) 2](2) are reported. The utilized sterically …
[Co (LSal, 2-Ph) 2](1) and [Co (LNph, 2-Ph) 2](2) are reported. The utilized sterically …