In the context of modular and rapid construction of molecular diversity and complexity for
applications in organic synthesis, biomedical and materials sciences, a generally useful …

Conspectus Chemo-and stereoselective transformations of polyborylalkanes are powerful
and efficient methods to access optically active molecules with greater complexity and …

The development of α, α-disubstituted crotylboronate reagents is reported. Chiral Brønsted
acid-catalyzed asymmetric aldehyde addition with the developed E-crotylboron reagent …

Abstract (E)‐δ‐Boryl‐substituted anti‐homoallylic alcohols are synthesized in a highly
diastereo‐and enantioselective manner from 1, 1‐di (boryl) alk‐3‐enes and aldehydes …

We report a dual function asymmetric catalysis by a chiral phosphoric acid catalyst that
controls both enantioselective addition of an achiral α‐vinyl allylboronate to aldehydes and …

A new copper‐catalyzed reaction for the stereo‐and regioselective synthesis of alkenyl
diboronates and allenyl boronates is presented. In this process propargyl derivatives of …

Allylboronic esters react readily with carbonyls and imines (π-electrophiles), but are
unreactive toward a range of other electrophiles. By addition of an aryllithium, the …

Abstract Skipped dienes (1, 4‐dienes) are widely distributed in a variety of biologically active
natural products. The synthesis of these skipped dienes is a relatively undeveloped area …

Organoboron compounds have found widespread application in everyday organic
synthesis. The Lewis acidic properties, non‐toxicity, stability, and easy commercial …

We report the highly diastereo‐and enantioselective preparation of (E)‐δ‐boryl‐substituted
anti‐homoallylic alcohols in two steps from terminal alkynes. This method consists of a …