Measuring methods of infinite dilution activity coefficients and a database for systems including water

K Kojima, S Zhang, T Hiaki - Fluid Phase Equilibria, 1997 - Elsevier
Experimental techniques for the determination of infinite dilution activity coefficients and their
improvements are reviewed. Generally, the measuring techniques can be classified as the …

[HTML][HTML] Trends in solvent impact on infinite dilution activity coefficients of solutes reviewed and visualized using an algorithm to support selection of solvents for …

T Brouwer, SRA Kersten, G Bargeman… - Separation and …, 2021 - Elsevier
The infinite dilution activity coefficient, γ i∞, is a frequently used molecular descriptor to pre-
select a solvent for various kinds of fluid separations. Unfortunately, information related to …

Development of alternative methanol/dimethyl carbonate separation systems by extractive distillation—A holistic approach

CC Hu, SH Cheng - Chemical Engineering Research and Design, 2017 - Elsevier
Separation of dimethyl carbonate (DMC) with methanol (MeOH) is fundamentally difficult as
DMC forms an azeotrope with MeOH. In this context, a holistic, three-tiered approach was …

Vapor pressures of methyl tert-butyl ether, ethyl tert-butyl ether, isopropyl tert-butyl ether, tert-amyl methyl ether, and tert-amyl ethyl ether

MA Krähenbühl, J Gmehling - Journal of Chemical and …, 1994 - ACS Publications
The vapor pressures of methyl ieri-butyl ether, ethyl ieri-butyl ether, isopropyl ieri-butyl ether,
ieri-amyl methyl ether, and ieri-amyl ethyl ether were measured by ebulliometry or the static …

Solvent selection for cyclohexane− cyclohexene− benzene separation by extractive distillation using non-steady-state gas chromatography

A Vega, F Díez, R Esteban, J Coca - Industrial & engineering …, 1997 - ACS Publications
The infinite-dilution activity coefficients of cyclohexane, cyclohexene, and benzene in N, N-
dimethylformamide, N-methylpyrrolidone, N, N-dimethylacetamide, phenyl acetate, and …

Distillation, azeotropic, and extractive

MF Doherty, JP Knapp - Kirk‐Othmer Encyclopedia of …, 2000 - Wiley Online Library
Many industrial processes depend on efficient methods for separating azeotropic, close‐
boiling, or other low relative volatility mixtures. Ordinary distillation is typically either …

Effects of lithium nitrate on the vapor− liquid equilibria of methyl acetate+ methanol and ethyl acetate+ ethanol

M Topphoff, J Kiepe, J Gmehling - Journal of Chemical & …, 2001 - ACS Publications
Isobaric vapor− liquid equilibrium data for the system methyl acetate (1)+ methanol (2)+
lithium nitrate (3) and ethyl acetate (1)+ ethanol (2)+ lithium nitrate (3) at constant salt …

Application of infinite dilution activity coefficients for determining binary equation of state parameters

CS Schacht, L Zubeir, TW de Loos… - Industrial & Engineering …, 2010 - ACS Publications
Infinite dilution activity coefficients can be determined relatively fast from several
experimental techniques. Literature values for the infinite dilution activity coefficients are …

Measurements of activity coefficients at infinite dilution in vegetable oils and capric acid using the dilutor technique

PC Belting, J Rarey, J Gmehling, R Ceriani… - Fluid phase …, 2014 - Elsevier
This paper reports experimental activity coefficients at infinite dilution, γ i∞, for methanol,
ethanol and n-hexane in three refined vegetable oils (soybean, sunflower, and rapeseed …

Application of IR-spectroscopy in thermodynamic investigations of associating solutions

N Asprion, H Hasse, G Maurer - Fluid phase equilibria, 2003 - Elsevier
This paper presents results from a study on the use of IR-spectroscopic information in the
development of thermodynamic models of H-bonding solutions. It is based on a previous …