Bioorthogonal chemistry is a promising toolbox for dissecting biological processes in the
native environment. Recently, bioorthogonal reactions have attracted considerable attention …

Synthetic biology aims at designing new biological functions from first principles. These new
designs allow to expand the natural solution space and overcome the limitations of naturally …

Nanozyme has emerged as promising alternative to natural enzyme during recent years.
Currently, laccase nanozyme is mainly limited to Cu-containing materials with catalytic Cu …

Considering the intrinsic toxicities of transition metals, their incorporation into drug therapies
must operate at minimal amounts while ensuring adequate catalytic activity within complex …

Cerium photoredox catalysis has emerged as a powerful strategy to activate molecules
under mild conditions. Radical intermediates are formed using visible light and simple …

Artificial enzymes with new-to-nature reactivity are highly desirable to expand the repertoire
of biocatalysis for sustainable synthesis. To this end, artificial photoenzymes embedded with …

Since polyoxometalates (POMs) can undergo reversible multi‐electron redox
transformations, they have been used to modulate the electronic environment of metal …

Substrate selectivity is one of the most attractive features of natural enzymes from their “bind-
to-catalyze” working flow and is thus a goal for the development of synthetic enzyme mimics …

Artificial photoenzymes with novel catalytic modes not found in nature are in high demand;
yet, they also present significant challenges in the field of biocatalysis. In this study, a …

Artificial metalloenzymes (ArMs) are gaining much attention in life sciences. However, the
function of the present ArMs for disease treatment is still in its infancy, which may impede the …