Reactivity of gold complexes towards elementary organometallic reactions

M Joost, A Amgoune… - Angewandte Chemie …, 2015 - Wiley Online Library
For a while, the reactivity of gold complexes was largely dominated by their Lewis acid
behavior. In contrast to the other transition metals, the elementary steps of organometallic …

Theoretical chemistry of gold. III

P Pyykkö - Chemical Society Reviews, 2008 - pubs.rsc.org
Gold is an element whose unique properties are strongly influenced by relativistic effects. A
large body of appropriate calculations now exists and its main conclusions are summarized …

Dual visible light photoredox and gold-catalyzed arylative ring expansion

X Shu, M Zhang, Y He, H Frei… - Journal of the American …, 2014 - ACS Publications
A combination of visible light photocatalysis and gold catalysis is applied to a ring expansion–
oxidative arylation reaction. The reaction provides an entry into functionalized cyclic ketones …

Gold‐Catalyzed Allylation of Aryl Boronic Acids: Accessing Cross‐Coupling Reactivity with Gold

MD Levin, FD Toste - Angewandte Chemie International …, 2014 - Wiley Online Library
A sp3–sp2 C C cross‐coupling reaction catalyzed by gold in the absence of a sacrificial
oxidant is described. Vital to the success of this method is the implementation of a bimetallic …

A spectrophotometric study of aqueous Au (III) halide–hydroxide complexes at 25–80 C

A Usher, DC McPhail, J Brugger - Geochimica et Cosmochimica Acta, 2009 - Elsevier
The mobility and transport of gold in low-temperature waters and brines is affected by the
aqueous speciation of gold, which is sensitive in particular to pH, oxidation and halide …

Advances in the coordination chemistry of nitrogen ligand complexes of coinage metals

AA Mohamed - Coordination Chemistry Reviews, 2010 - Elsevier
Coinage metals nitrogen chemistry has not been studied extensively until recently. The
focus of this review is the base-and halide-free complexes of the monoanionic nitrogen …

Macrocycles, catenanes, oligomers and polymers in gold chemistry

RJ Puddephatt - Chemical Society Reviews, 2008 - pubs.rsc.org
A critical review is given of the chemistry of macrocycles, catenanes, oligomers and
polymers in gold chemistry. Because gold centres are typically labile towards ligand …

An arsenic-driven pump for invisible gold in hydrothermal systems

GS Pokrovski, C Escoda, M Blanchard… - Geochemical …, 2021 - hal.science
Pyrite (FeS 2), arsenopyrite (FeAsS) and löllingite (FeAs 2) are exceptional gold
concentrators on Earth; yet the exact redox and structural state of this" invisible" gold and the …

Targeting of nuclear factor-κB and proteasome by dithiocarbamate complexes with metals

B Cvek, Z Dvorak - Current pharmaceutical design, 2007 - ingentaconnect.com
Dithiocarbamates and their complexes with transition metals have been used as common
pesticides, vulcanizing or analytical agents for decades. These compounds are one of the …

A thermally stable gold (III) hydride: synthesis, reactivity, and reductive condensation as a route to gold (II) complexes.

DA Roşca, DA Smith, DL Hughes… - … Chemie (International ed …, 2012 - europepmc.org
Going for gold: The first thermally stable gold (III) hydride [(CNC)* AuH] is presented. It
undergoes regioselective insertions with allenes to give gold (III) vinyl complexes, and …