Solvent Effects on the Structural and Magnetic Properties of FeIII Spin-Crossover Complexes

U Habarakada, T Boonprab, P Harding… - Crystal Growth & …, 2022 - ACS Publications
Molecular devices based on spin-crossover (SCO) compounds are important targets for
molecular electronics. In this study, six air-stable FeIII complexes have been prepared:[Fe …

Structure–function correlations in mononuclear manganese (iii) spin crossover systems with a big conjugated hexadentate Schiff-base ligand

SZ Zhao, CY Qin, S Wang, M Yamashita, YH Li… - Dalton …, 2020 - pubs.rsc.org
This paper reports the syntheses, crystal structures and magnetic properties of spin
crossover (SCO) salts of formulae [Mn (naphth-sal-N-1, 5, 8, 12)] SbF6 (1),[Mn (naphth-sal-N …

Gradual two-step and room temperature spin crossover in Mn (III) complexes with nitro-substituted ligand

SZ Zhao, ZM Yu, CY Qin, PY Xu, YT Wang, YH Li… - Inorganica Chimica …, 2022 - Elsevier
The syntheses, crystal structures and magnetic properties of spin crossover (SCO) salts of
formula [Mn (5-NO 2-sal-N-1, 5, 8, 12)] AsF 6 (1) and [Mn (5-NO 2-sal-N-1, 5, 8, 12)] SbF 6 …

Anion-driven supramolecular modulation of spin-crossover properties in mononuclear iron (iii) Schiff-base complexes

ZM Yu, SZ Zhao, YT Wang, PY Xu, CY Qin, YH Li… - Dalton …, 2021 - pubs.rsc.org
A series of Fe (III) complexes [Fe (5-F-sal-N-1, 4, 7, 10)] Y (Y= PF6− for 1, Y= ClO4− for 2, Y=
I− for 3 and Y= NO3− for 4) have been prepared. Single-crystal X-ray crystallographic …

Thermodynamics of spin crossover in a bis (terpyridine) cobalt (II) complex featuring a thioether functionality

LF Lobato, S Ciattini, A Gallo, RAA Cassaro… - Dalton …, 2024 - pubs.rsc.org
In this contribution, a terpyridine-based ligand bearing a thioether functionality is used to
prepare a new cobalt (II) spin crossover complex:[Co (TerpyPhSMe) 2](PF6) 2 (1), where …

High temperature anionic Fe (iii) spin crossover behavior in a mixed-valence Fe (ii)/Fe (iii) complex

ZJ Ouyang, XY Mo, JQ Ye, XX Yu, SY Huang… - Dalton …, 2021 - pubs.rsc.org
Two ion-pair Fe (III) complexes (PPh4)[FeIII (HATD) 2]· 2H2O (1, H3ATD= azotetrazolyl-2, 7-
dihydroxynaphthalene) and [FeII (phen) 3][FeIII (HATD) 2] 2· 3DMA· 3.5 H2O (2, phen= 1, 10 …

A novel fabrication of [Fe(HB(pz)3)2]@MIL-101 hybrid material via diffusion and the lower temperature shift on its spin transition behavior

T Zhao, M Dong, Y Zhao - Applied Physics A, 2019 - Springer
Abstract [Fe (HB (pz) 3) 2], a well-studied spin-crossover (SCO) complex, has been
entrapped in NH 2-MIL-101 (Al) metal–organic framework (MOF) via gas diffusion …