Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes

AC Ghosh, C Duboc, M Gennari - Coordination Chemistry Reviews, 2021 - Elsevier
Transition metal-driven small molecule activation is essential for the production of fuels and
chemicals or energy supply. The use of multimetallic catalysts, where two or more metal …

Role of carbon monoxide in host–gut microbiome communication

CP Hopper, LK De La Cruz, KV Lyles… - Chemical …, 2020 - ACS Publications
Nature is full of examples of symbiotic relationships. The critical symbiotic relation between
host and mutualistic bacteria is attracting increasing attention to the degree that the gut …

An alcove at the acetyl-CoA synthase nickel active site is required for productive substrate CO binding and anaerobic carbon fixation

S Wiley, C Griffith, P Eckert, AP Mueller, R Nogle… - Journal of Biological …, 2024 - jbc.org
One of the seven natural CO 2 fixation pathways, the anaerobic Wood-Ljungdahl pathway
(WLP) is unique in generating CO as a metabolic intermediate, operating through …

Acetogens: biochemistry, bioenergetics, genetics, and biotechnological potential

VG Debabov - Microbiology, 2021 - Springer
The review discusses the present-day data on the biochemistry, bioenergetics, and genetics
of acetogens, as well as their biotechnological potential. Acetogens are anaerobic gram …

13C Electron Nuclear Double Resonance Spectroscopy Shows Acetyl-CoA Synthase Binds Two Substrate CO in Multiple Binding Modes and Reveals the …

CD James, S Wiley, SW Ragsdale… - Journal of the American …, 2020 - ACS Publications
EPR and Electron Nuclear Double Resonance spectroscopies here characterize CO binding
to the active-site A cluster of wild-type (WT) Acetyl-CoA Synthase (ACS) and two variants …

Batch and semi-continuous fermentation with Parageobacillus thermoglucosidasius DSM 6285 for H2 production

MS Ardila, H Aliyu, P de Maayer… - Biotechnology for Biofuels …, 2025 - Springer
Background Parageobacillus thermoglucosidasius is a facultatively anaerobic thermophile
that is able to produce hydrogen (H2) gas from the oxidation of carbon monoxide through …

Carbon dioxide utilization—bioelectrochemical approaches

CM Cordas, JJG Moura, A Escapa… - Enzymes for Solving …, 2021 - Springer
CO 2 level increase in the planet is a major concern and utilization, mitigation and
transformation of CO 2 in useful compounds is of great interest. This chapter points to an …

[HTML][HTML] Theoretical Studies of Acetyl-CoA Synthase Catalytic Mechanism

M Jaworska, P Lodowski - Catalysts, 2022 - mdpi.com
DFT calculations were performed for the A-cluster from the enzyme Acetyl-CoA synthase
(ACS). The acid constants (pK a), reduction potentials, and pH-dependent reduction …

Ацетогены: биохимия, энергетика, генетика, биотехнологический потенциал

ВГ Дебабов - Микробиология, 2021 - elibrary.ru
Ацетогены–это анаэробные грамположительные бактерии, способные к росту на
газовых субстратах–СО 2, СО, Н 2. Отличительной особенностью этих бактерий …

Spectroscopic and Enzymatic Investigations into the Organometallic Incorporation of Methyl and Carbonyl Substrates by Acetyl-Coenzyme A Synthase from Moorella …

S Wiley - 2020 - deepblue.lib.umich.edu
The Wood-Ljungdahl pathway of acetogenesis is an ancient metabolic pathway found in
both bacteria and archaea that allows for the reversible reduction and fixation of CO2 into …