Transition metal-catalysed functionalizations of inert C–H bonds to construct C–C bonds
represent an ideal route in the synthesis of valuable organic molecules. Fine tuning of …

The pyrrolo [1, 2-a] indole unit is a privileged heterocycle found in numerous natural
products and has been shown to exhibit diverse pharmacological properties. Thus, recent …

A rhodium-catalyzed annulation between ethyl benzimidates and α-aroyl sulfur ylides was
developed, affording a series of pyrano [4, 3, 2-ij] isoquinoline derivatives in moderate to …

A novel Rh-catalyzed cascade C–H activation/annulation of 2-arylbenzimidazoles with
maleimides is reported. Rapid chemoselective access to two structurally distinct succinimide …

A Rh (III)-catalyzed dehydrogenative annulation and spirocyclization of 2-arylindoles and 2-
(1 H-pyrazol-1-yl)-1 H-indole with maleimides is described. The cascade protocol provided …

The Rh (III)-catalyzed C–H oxidative alkylation of aniline derivatives with readily available
secondary allyl alcohols using a pyrimidine-directing group, leading to the production of β …

Rhodium-catalyzed substrate-tunable oxidative annulation and spiroannulation reactions of
2-arylindoles with benzoquinone leading to 9 H-dibenzo [a, c] carbazol-3-ols and new …

Rhodium-catalysed cross-dehydrogenative coupling (CDC) has received considerable
attention in recent years. This modern technology has been considered as an attractive …

Readily available N-carbamoyl indolines can be converted into highly valuable 2-alkenyl
and 2-alkyl indoles in a one-pot reaction, through an autotandem catalytic cascade …

A formation of fused tricyclic [1, 3] oxazino [3, 4‐a] indol‐1‐ones and dihydropyrimido [1, 6‐
a] indol‐1 (2H)‐ones via Rh (III)‐catalyzed [3+ 3] or [4+ 2] annulation of N‐methoxy‐1H …