Chemical versatility of azide radical: journey from a transient species to synthetic accessibility in organic transformations

M Shee, NDP Singh - Chemical Society Reviews, 2022 - pubs.rsc.org
The generation of azide radical (N3˙) occurs from its precursors primarily via a single
electron transfer (SET) process or homolytic cleavage by chemical methods or advanced …

Experimental techniques in gas-phase ion thermochemistry

KM Ervin - Chemical Reviews, 2001 - ACS Publications
Ion thermochemistry is of great practical importance to mass spectrometry. Ion source
intensities and fragmentation patterns in mass spectra are intimately related to ion …

Photoelectron spectroscopy of CN, NCO, and NCS

SE Bradforth, EH Kim, DW Arnold… - The Journal of chemical …, 1993 - pubs.aip.org
The 266 nm photoelectron spectra of CN−, NCO−, and NCS− have been recorded with a
pulsed time‐of‐flight photoelectron spectrometer. The photoelectron spectrum of CN− has …

All-nitrogen chemistry: how far are we from N60?

PC Samartzis, AM Wodtke - International Reviews in Physical …, 2006 - Taylor & Francis
Two hundred years of research have produced only a handful of synthesized all-nitrogen
molecules and ions but a lot of stable N n candidates are waiting to be detected …

Imaging chemical reactions–3D velocity mapping

AI Chichinin, KH Gericke, S Kauczok… - International Reviews in …, 2009 - Taylor & Francis
Visualising a collision between an atom or a molecule or a photodissociation (half-collision)
of a molecule on a single particle and single quantum level is like watching the collision of …

Fast beam photodissociation spectroscopy and dynamics of the vinoxy radical

DL Osborn, H Choi, DH Mordaunt, RT Bise… - The Journal of …, 1997 - pubs.aip.org
The spectroscopy and photodissociation dynamics of the vinoxy (CH2CHO) radical B̃ (2A
″)← X̃ (2A ″) transition have been investigated by fast beam photofragment translational …

Photodissociation dynamics of the N3 radical

RE Continetti, DR Cyr, DL Osborn, DJ Leahy… - The Journal of …, 1993 - pubs.aip.org
The dissociation dynamics of the B ̃ 2Σ u+ state of N3 were investigated using fast radical
beam photodissociation coupled with a new coincidence wedge‐and‐strip‐anode particle …

Invited review article: photofragment imaging

AG Suits - Review of Scientific Instruments, 2018 - pubs.aip.org
Photodissociation studies in molecular beams that employ position-sensitive particle
detection to map product recoil velocities emerged thirty years ago and continue to evolve …

Photodissociation spectroscopy and dynamics of the N2O2 anion

DL Osborn, DJ Leahy, DR Cyr… - The Journal of chemical …, 1996 - pubs.aip.org
The spectroscopy and dissociation dynamics of the N2O− 2 (C2 v) anion have been
investigated using the technique of fast ion beam translational spectroscopy. A newly …

High-level ab initio studies of unimolecular dissociation of the ground-state N3 radical

P Zhang, K Morokuma, AM Wodtke - The Journal of chemical physics, 2005 - pubs.aip.org
For nitrogen, unlike most elements, the energy of a N–N single bond is substantially less
than one-third, and the energy of a NvN double bond is substantially less than twothirds of a …