Recent advances in the design and applications of platinum-based supramolecular architectures and macromolecules

BZ Momeni, AS Abd-El-Aziz - Coordination Chemistry Reviews, 2023 - Elsevier
Platinum complexes have attracted increasing attention because of their intriguing
photophysical and anticancer activities. They are considered excellent building blocks for …

Supramolecular organometallic chemistry: the platinum (iv) paradigm

RJ Puddephatt - Dalton Transactions, 2022 - pubs.rsc.org
Supramolecular chemistry and the chemistry of alkyl derivatives of the transition metals are
both topics of considerable current interest, but the combination of the two fields is still …

Oxidative addition of halogens to a Cycloneophylplatinum (II) complex and evidence for C–H bond activation at Platinum (IV)

MA Fard, RJ Puddephatt - Journal of Organometallic Chemistry, 2020 - Elsevier
The reactions of halogens or their equivalent with the cycloneophylplatinum (II) complex [Pt
(CH 2 CMe 2 C 6 H 4)(phen*)], phen*= 3, 4, 7, 8-tetramethyl-1, 10-phenanthroline, are …

Oxidative addition of halogens to a Dineophylplatinum (II) Complex: Halogen complexes and fluxional Platinum (IV) complexes

ME Moustafa, MA Fard, RJ Puddephatt - Journal of Organometallic …, 2023 - Elsevier
The reactions of [Pt (CH 2 CMe 2 Ph) 2 (phen*)], 2, phen*= 3, 4, 7, 8-tetramethyl-1, 10-
phenanthroline, with halogens X 2 or their equivalents [PhICl 2 (as a Cl 2 equivalent), Br 2 …

Organoplatinum Chemistry Related to Alkane Oxidation: The Effect of a Nitro Substituent in Ligands Having an Appended Phenol Group

A Abo-Amer, ME Moustafa, PD Boyle, RJ Puddephatt - Inorganics, 2024 - mdpi.com
The organoplatinum chemistry of the ligands 2-C5H4N-CH2-NH-C6H3-2-OH-5-X (L1, X= H;
L3, X= NO2) and 2-C5H4N-CH= N-C6H3-2-OH-5-X (L2, X= H; L4, X= NO2), which contain …

Ligand-Mediated C–Br Oxidative Addition to Cycloplatinated (II) Complexes and Benzyl-Me C–C Bond Reductive Elimination from a Cycloplatinated (IV) Complex

M Bavi, SM Nabavizadeh, FN Hosseini, F Niknam… - ACS …, 2020 - ACS Publications
Reaction of the Pt (II) complexes [PtMe2 (pbt)], 1a,(pbt= 2-(2-pyridyl) benzothiazole) and
[PtMe (C^ N)(PPh2Me)][C^ N= deprotonated 2-phenylpyridine (ppy), 1b, or deprotonated …

The remarkable effects of a ligand nitro substituent in organoplatinum chemistry related to activation of dioxygen or reductive elimination of methane

A Abo-Amer, PD Boyle, RJ Puddephatt - Polyhedron, 2022 - Elsevier
A comparison is made of the chemistry of platinum with the ligands 2-C 5 H 4 NCH 2 NH-C 6
H 3-2-OH-5-R, when R= H (L) or NO 2 (L1) in order to determine the effect of the nitro …

Complexes Containing a Phenol–Platinum (II) Hydrogen Bond: Synthons for Supramolecular Self‐Assembly and Precursors for Hydridoplatinum (IV) Complexes

A Behnia, MA Fard, PD Boyle… - European Journal of …, 2019 - Wiley Online Library
The cycloneophylplatinum (II) complexes [Pt (CH2CMe2C6H4)(κ2‐NN′‐2‐C5H4NCH2‐
NH‐R], R= 2‐C6H4OH, 1; R= 3‐C6H4OH, 2; R= 4‐C6H4OH, 3, and [Pt …

Metal–Organic Cubane Cage with Trimethylplatinum (IV) Vertices

Z Hendi, S Jamali, S Mahmoudi, H Samouei… - Inorganic …, 2021 - ACS Publications
Herein we describe the synthesis and characterization of the first platinum (IV) metal–
organic cage [(Me3PtIV) 8 (byp) 12](OTf) 8 (2), in which the organometallic moieties …

Models for cooperative catalysis: Oxidative addition reactions of dimethylplatinum (II) complexes with ligands having both NH and OH functionality

M Azizpoor Fard, A Behnia, RJ Puddephatt - ACS omega, 2019 - ACS Publications
The role of NH and OH groups in the oxidative addition reactions of the complexes [PtMe2
(κ2-N, N′-L)], L= 2-C5H4NCH2NH-x-C6H4OH [3, x= 2, L= L1; 4, x= 3, L= L2; 5, x= 4, L= L3] …