Frontal polymerizations: from chemical perspectives to macroscopic properties and applications

BA Suslick, J Hemmer, BR Groce, KJ Stawiasz… - Chemical …, 2023 - ACS Publications
The synthesis and processing of most thermoplastics and thermoset polymeric materials rely
on energy-inefficient and environmentally burdensome manufacturing methods. Frontal …

Photoisomerizable azobenzene dyes incorporated into polymers and dendrimers. Influence of the molecular aggregation on the nonlinear optical properties

F Cuetara-Guadarrama, M Vonlanthen… - Dyes and …, 2021 - Elsevier
In this feature article, an overview of azobenzene containing dyes, polymers and dendrimers
is presented. The main focus is on the results obtained in our research group during the last …

Poly(N-vinylcaprolactam) nanocomposites containing nanocrystalline cellulose: a green approach to thermoresponsive hydrogels

R Sanna, E Fortunati, V Alzari, D Nuvoli, A Terenzi… - Cellulose, 2013 - Springer
In this work, we report on the synthesis and characterization of thermoresponsive poly (N-
vinylcaprolactam), PNVCL, nanocomposite hydrogels containing nanocrystalline cellulose …

Polymer Hydrogels and Frontal Polymerization: A Winning Coupling

A Mariani, G Malucelli - Polymers, 2023 - mdpi.com
Polymer hydrogels are 3D networks consisting of hydrophilic crosslinked macromolecular
chains, allowing them to swell and retain water. Since their invention in the 1960s, they have …

Synthesis and characterization of poly (2-hydroxyethylacrylate)/β-cyclodextrin hydrogels obtained by frontal polymerization

D Nuvoli, V Alzari, L Nuvoli, M Rassu, D Sanna… - Carbohydrate …, 2016 - Elsevier
For the first time, the synthesis of polymeric hydrogels containing cyclodextrins (CDs)
obtained by frontal polymerization (FP) is reported. In particular, the effects of CDs on poly (2 …

PEGDA‐based luminescent polymers prepared by frontal polymerization

J Illescas, YS Ramírez‐Fuentes… - Journal of Polymer …, 2015 - Wiley Online Library
Frontal polymerization (FP) of poly (ethylene glycol) diacrylate (PEGDA) was carried out
using benzoyl peroxide (BPO) as radical initiator. In addition, a pyrene containing monomer …

Semi‐interpenetrating polymer networks based on crosslinked poly(N‐isopropyl acrylamide) and methylcellulose prepared by frontal polymerization

A Mariani, L Nuvoli, D Sanna, V Alzari… - Journal of Polymer …, 2018 - Wiley Online Library
In this work, semi‐interpenetrating gels of poly (N‐isopropyl acrylamide) and
methylcellulose were successfully synthesized by using the Frontal Polymerization (FP) …

Design of novel luminescent porphyrins bearing donor–acceptor groups

C Caicedo, G Zaragoza-Galán, J Crusats… - Journal of Porphyrins …, 2014 - World Scientific
In this work, we report the synthesis and characterization of a novel series of porphyrins,
some of them bearing donor-acceptor groups. meso-substituted free-base porphyrins: 5-(4 …

Polymer Hydrogels and Frontal Polymerization: A Winning Coupling

G Malucelli, A Mariani - 2023 - preprints.org
Polymer hydrogels are 3D networks consisting of hydrophilic crosslinked macromolecular
chains, able to swell and retain water. Since their invention in the 1960s, they have become …

Theoretical study of novel azo-tetraphenylporphyrins: potential photovoltaic materials

E Hernandez-Marin, C Caicedo, E Rivera… - The Journal of …, 2014 - ACS Publications
A density functional theory study was performed to analyze the electron donor–acceptor
properties of the cis and trans isomers of a novel azobenzene-containing …