Stereoregular polymerization of acyclic terpenes

DH Lamparelli, M Winnacker… - ChemPlusChem, 2022 - Wiley Online Library
The growing environmental pollution and the expected depleting of fossil resources have
sparked interest in recent years for polymers obtained from monomers originating from …

Polymerization of Bio‐Derived Conjugated Dienes with Rare‐Earth‐Metal Complexes

F You, W Shi, X Yan, X Wang… - Chemistry–An Asian …, 2022 - Wiley Online Library
The reliance of both our life and industry on fossil resource and the alarming accumulation
of polymeric materials in the environment have presented huge challenges to sustainable …

[HTML][HTML] Introducing random bio-terpene segments to high cis-polybutadiene: making elastomeric materials more sustainable

JL González-Zapata, FJ Enríquez-Medrano… - RSC …, 2020 - pubs.rsc.org
In this work, we explore the statistical copolymerization of 1, 3-butadiene with the terpenic
monomers myrcene and farnesene, carried out via coordination polymerization using a …

[HTML][HTML] Coordinative Chain Transfer Polymerization of Sustainable Terpene Monomers Using a Neodymium-Based Catalyst System

T Córdova, FJ Enríquez-Medrano, EM Cartagena… - Polymers, 2022 - mdpi.com
The present investigation involves the coordinative chain transfer polymerization (CCTP) of
biobased terpenes in order to obtain sustainable polymers from myrcene (My) and …

[HTML][HTML] Bio-elastomer nanocomposites reinforced with surface-modified graphene oxide prepared via in situ coordination polymerization

A Bahena, I Magana, HRL González, R Handa… - RSC …, 2020 - pubs.rsc.org
This article proposes a method to produce bio-elastomer nanocomposites, based on
polyfarnesene or polymyrcene, reinforced with surface-modified graphene oxide (GO). The …

[HTML][HTML] Synthesis and vulcanization of polymyrcene and polyfarnesene bio-based rubbers: influence of the chemical structure over the vulcanization process and …

A Banda-Villanueva, JL González-Zapata… - Polymers, 2022 - mdpi.com
The overuse of fossil-based resources to produce thermoplastic materials and rubbers is
dramatically affecting the environment, reflected in its clearest way as global warming. As a …

[HTML][HTML] Bio-elastomers based on polyocimene synthesized via coordination polymerization using neodymium-based catalytic systems

L Valencia, FJ Enríquez-Medrano, HRL González… - RSC …, 2020 - pubs.rsc.org
Towards the development of eco-friendly alternatives of elastomeric materials, which can
replace petroleum-based materials, it is crucial to explore different monomers and catalytic …

[HTML][HTML] Fully bio-based elastomer nanocomposites comprising polyfarnesene reinforced with plasma-modified cellulose nanocrystals

I Magaña, D Georgouvelas, R Handa… - Polymers, 2021 - mdpi.com
This article proposes a process to prepare fully bio-based elastomer nanocomposites based
on polyfarnesene and cellulose nanocrystals (CNC). To improve the compatibility of …

Study on two different dithiobenzoates effectiveness in bulk RAFT polymerization of β-myrcene

CA Uriel, CF Cristian, ML Gumersindo… - Journal of Polymer …, 2024 - Springer
The study aimed to evaluate the impact of two chain transfer controllers, ethyl 2-(
phenylcarbonothiolthio)-2-phenylacetate (EPPA) and 2-(4-methoxyphenylcarbonothiolthio) …

Rutas de síntesis para la obtención de elastómeros a base de monómeros extraídos de fuente vegetal

VAC Tovar, A Rubio, A Sáenz, L Farías-Cepeda - Afinidad, 2022 - raco.cat
La creciente demanda de productos de fuente sintética ha causado un incremento en los
niveles de contaminación de aire, suelos, así como mares y océanos. La implementación de …