Carbocatalysis in liquid‐phase reactions

DS Su, G Wen, S Wu, F Peng… - Angewandte Chemie …, 2017 - Wiley Online Library
There is broad interest in metal‐free catalysis for sustainable chemistry. Carbocatalysis is a
“green” option for catalytic transformations in the gas phase as well as in the liquid phase …

Conversion of lignocellulosic biomass-derived compounds to 2-ethylhexanol: a review

C Sun, S Zhang, B Gao, T Yang, Y Wang… - Environmental …, 2024 - Springer
The demand for 2-ethylhexanol is rising in several sectors, yet this chemical is actually
almost exclusively produced from petroleum resources, calling for sustainable alternatives …

Electrochemical conversion of muconic acid to biobased diacid monomers

JE Matthiesen, JM Carraher, M Vasiliu… - ACS Sustainable …, 2016 - ACS Publications
Electrocatalysis is evolving as a competitive alternative to conventional heterogeneous
catalysis for the conversion of platform chemicals from biomass. Here, we demonstrate the …

Enzymatic hydrolysis in the green production of bacterial cellulose nanocrystals

C Rovera, M Ghaani, N Santo… - ACS Sustainable …, 2018 - ACS Publications
In this study, we extensively describe experimental models, with correlating experimental
conditions, which were used to investigate the enzymatic hydrolysis of bacterial cellulose …

Biocompatible α‐Methylenation of Metabolic Butyraldehyde in Living Bacteria

JA Dennis, NW Johnson, TW Thorpe… - Angewandte Chemie …, 2023 - Wiley Online Library
Small molecule organocatalysts are abundant in all living organisms. However, their use as
organocatalysts in cells has been underexplored. Herein, we report that organocatalytic …

Designer Micelles Accelerate Flux Through Engineered Metabolism in E. coli and Support Biocompatible Chemistry

S Wallace, EP Balskus - Angewandte Chemie, 2016 - Wiley Online Library
Synthetic biology has enabled the production of many value‐added chemicals via microbial
fermentation. However, the problem of low product titers from recombinant pathways has …

Interfacing non-enzymatic catalysis with living microorganisms

JC Sadler, JA Dennis, NW Johnson… - RSC Chemical Biology, 2021 - pubs.rsc.org
Interfacing non-enzymatic catalysis with cellular metabolism is emerging as a powerful
approach to produce a range of high value small molecules and polymers. In this review, we …

Merger of whole cell biocatalysis with organocatalysis upgrades alcohol feedstocks in a mild, aqueous, one-pot process

KN Stewart, EG Hicks, DW Domaille - ACS Sustainable Chemistry …, 2020 - ACS Publications
Biosynthetic methods have the potential to deliver value-added chemicals from renewable
feedstocks. However, despite major advances in metabolic engineering and synthetic …

A one-pot biocatalytic and organocatalytic cascade delivers high titers of 2-ethyl-2-hexenal from n-butanol

KN Stewart, DW Domaille - Reaction Chemistry & Engineering, 2022 - pubs.rsc.org
Biocatalysis provides facile access to selective chemical transformations and helps satisfy
sustainable chemical production criteria. However, the reaction scope of biocatalysts is …

Multicatalytic, light-driven upgrading of butanol to 2-ethylhexenal and hydrogen under mild aqueous conditions

GR Hafenstine, K Ma, AW Harris, O Yehezkeli… - ACS …, 2017 - ACS Publications
Microbes produce low-molecular-weight alcohols from sugar, but these metabolites are
difficult to separate from water and possess relatively low heating values. A combination of …