Carbene radicals in transition-metal-catalyzed reactions
Discovered as organometallic curiosities in the 1970s, carbene radicals have become a
staple in modern-day homogeneous catalysis. Carbene radicals exhibit nucleophilic radical …
staple in modern-day homogeneous catalysis. Carbene radicals exhibit nucleophilic radical …
Charge frustration in ligand design and functional group transfer
Molecules with different resonance structures of similar importance, such as
heterocumulenes and mesoionics, are prominent in many applications of chemistry …
heterocumulenes and mesoionics, are prominent in many applications of chemistry …
Cooperative bond activation reactions with carbene complexes
KS Feichtner, VH Gessner - Chemical Communications, 2018 - pubs.rsc.org
Metal–ligand cooperation has emerged as a powerful concept in bond activation chemistry
and catalysis. Here, both the metal and the ligand are directly involved in the bond breaking …
and catalysis. Here, both the metal and the ligand are directly involved in the bond breaking …
[2+ 2] cycloadditions with an iron carbene: a critical step in enyne metathesis
MR Hoffbauer, VM Iluc - Journal of the American Chemical …, 2021 - ACS Publications
Ruthenium carbenes, famously used in olefin metathesis, have impacted numerous
research areas, ranging from synthesis to materials and biology. Although in the same group …
research areas, ranging from synthesis to materials and biology. Although in the same group …
Cataloguing a renaissance in late transition metal PCcarbeneP pincer complexes
RA Manzano, RD Young - Coordination Chemistry Reviews, 2021 - Elsevier
The emergence of the PCP pincer ligand as a platform to enhance or allow challenging
bond activations and catalysis is an important development in coordination chemistry. Within …
bond activations and catalysis is an important development in coordination chemistry. Within …
Ruthenium (II) porphyrin quinoid carbene complexes: synthesis, crystal structure, and reactivity toward carbene transfer and hydrogen atom transfer reactions
Reactivity study of novel metal carbene complexes can offer new opportunities in catalytic
carbene transfer reactions as well as in other synthetic protocols. Metal complexes with …
carbene transfer reactions as well as in other synthetic protocols. Metal complexes with …
An Isolable Mononuclear Palladium (I) Amido Complex
Mononuclear Pd (I) species are putative intermediates in Pd-catalyzed reactions, but our
knowledge about them is limited due to difficulties in accessing them. Herein, we report the …
knowledge about them is limited due to difficulties in accessing them. Herein, we report the …
E–H (E= B, Si, Ge) bond activation of pinacolborane, silanes, and germanes by nucleophilic palladium carbene complexes
CC Comanescu, VM Iluc - Chemical Communications, 2016 - pubs.rsc.org
The reactivity of two nucleophilic palladium carbenes,[PC (sp2) P] Pd (PMe3) and [PC (sp2)
P] Pd (PPh3), where [PC (sp2) P]= bis [2-(di-iso-propylphosphino) phenyl] methylene …
P] Pd (PPh3), where [PC (sp2) P]= bis [2-(di-iso-propylphosphino) phenyl] methylene …
Reactivity umpolung (reversal) of ligands in transition metal complexes
RH Morris - Chemical Society Reviews, 2024 - pubs.rsc.org
The success and power of homogeneous catalysis derives in large part from the wide choice
of transition metal ions and their ligands. This tutorial review introduces examples where the …
of transition metal ions and their ligands. This tutorial review introduces examples where the …
Ln (II) and Ca (II) NC sp3 N pincer type diarylmethanido complexes–promising catalysts for C–C and C–E (E= Si, P, N, S) bond formation
DO Khristolyubov, DM Lyubov, AS Shavyrin… - Inorganic Chemistry …, 2020 - pubs.rsc.org
Ln (II)(Ln= Yb, Sm) and Ca (II)[NCsp3N] pincer type diarylmethanido complexes [2, 2′-(4-
MeC6H3NMe2) 2CH] 2M (M= Yb (2), Sm (3), Ca (4)) coordinated by a tridentate …
MeC6H3NMe2) 2CH] 2M (M= Yb (2), Sm (3), Ca (4)) coordinated by a tridentate …