Synthetic chlorins, possible surrogates for chlorophylls, prepared by derivatization of porphyrins

M Taniguchi, JS Lindsey - Chemical reviews, 2017 - ACS Publications
Chlorophylls make Earth green, are the central constituents in the engine of photosynthesis,
and not surprisingly have garnered immense attention. A chlorin, the core chromophore of a …

Metal complexes of porphyrinoids containing nonpyrrolic heterocycles

DW Thuita, C Brückner - Chemical Reviews, 2022 - ACS Publications
The replacement of one or more pyrrolic building block (s) of a porphyrin by a nonpyrrolic
heterocycle leads to the formation of so-called pyrrole-modified porphyrins (PMPs) …

Synthesis of aza-, oxa-, and thiaporphyrins and related compounds

Y Matano - Chemical Reviews, 2017 - ACS Publications
Chemical modification at the periphery with nitrogen or chalcogens is a highly promising
strategy to diversify the optical, electrochemical, magnetic, and coordination properties of the …

The Breaking and Mending of meso-Tetraarylporphyrins: Transmuting the Pyrrolic Building Blocks

C Bruckner - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Naturally occurring porphyrins and hydroporphyrins vary with respect to their
ring substituents and oxidation states, but their tetrapyrrolic frameworks remain fully …

Porphyrin macrocycle modification: Pyrrole ring-contracted or-expanded porphyrinoids

LD Costa, JIT Costa, AC Tomé - Molecules, 2016 - mdpi.com
In recent years, several synthetic strategies aiming at the peripheral functionalization of
porphyrins were developed. Particularly interesting are those involving the modification of β …

meso-Arylporpholactones and their Reduction Products

C Brückner, J Ogikubo, JR McCarthy… - The Journal of …, 2012 - ACS Publications
The rational syntheses of meso-tetraaryl-3-oxo-2-oxaporphyrins 5, known as
porpholactones, via MnO4–-mediated oxidations of the corresponding meso-tetraaryl-2, 3 …

Porphyriynes: 18-π-Conjugated Macrocycles Incorporating a Triple Bond

F Hao, T Zhang, D Yu, X Yang, HW Jiang, JC Xiao… - Organic …, 2022 - ACS Publications
Tetraphenylporphyriyne (Pyne1), a novel porphyrin analogue with a C≡ C bond
incorporated into an 18-π-conjugated system, has been created via cleavage of the N …

Carbaporphyrins and related systems. Synthesis, characterization, reactivity and insights into porphyrinoid aromaticity

TD Lash - Handbook of Porphyrin Science, 2010 - World Scientific
Contents Page 1 Contents Preface for Volumes 16–20 ix Preface for Volumes 1–10 x
Contributing Authors xi Contents of Volumes 1–20 xxix 74 / Carbaporphyrins and Related …

[PDF][PDF] Expanded bacteriochlorins

LP Samankumara, S Wells, M Zeller… - Angewandte Chemie …, 2012 - academia.edu
The Mg2+ complexes of bacteriochlorins (7, 8, 17, 18-tetrahydroporphyrins), such as
bacteriochlorophyll a (1), are used by phototrophic purple bacteria, heliobacteria, and green …

Siamese‐Twin Porphyrin: A Pyrazole‐Based Expanded Porphyrin of Persistent Helical Conformation

LK Blusch, Y Hemberger, K Pröpper… - … A European Journal, 2013 - Wiley Online Library
Abstract The 3+ 3‐type synthesis of a pyrazole‐based expanded porphyrin 22 H4, a
hexaphyrin analogue named Siamese‐twin porphyrin, and its homobimetallic diamagnetic …