Conspectus In organic synthesis, ligand-modified copper (I) hydride (CuH) complexes have
become well-known reagents and catalysts for selective reduction, particularly toward …

Homogeneous catalytic reactions are typically controlled by the stereoelectronic nature of
the ligand (s) that bind to the metal (s). The advantages of the so-called first coordination …

Chiral hydroxylamines are vital substances in bioscience and versatile subunits in the
preparation of a variety of functional molecules. However, asymmetric and non-asymmetric …

Comprehensive computational studies were carried out to explore the mechanisms of
enantioselective Cu/Pd and stereodivergent Cu/Ir dual-catalytic syntheses of α, α …

We report the incorporation of large substituents based on heavy main-group elements that
are atypical in ligand architectures to enhance dispersion interactions and, thereby …

Heterobimetallic bismuth–rhodium paddlewheel complexes with phenylglycine ligands
carrying TIPS-groups at the meta-positions of the aromatic ring exhibit outstanding levels of …

Propylene gas is produced worldwide by steam cracking on million‐metric‐ton scale per
year. It serves as a valuable starting material for π‐bond functionalization but is rarely …

Bis (diphenylphosphino) ethane (DPPE) and its synthetic analogues are important structural
motifs in organic synthesis, particularly as diphosphine ligands with a C2-alkyl-linker chain …

Cooperative dual catalysis is a powerful strategy for achieving unique reactivity by
combining catalysts with orthogonal modes of action. This approach allows for independent …

The selective introduction of perfluoro-tert-butyl group (PFtB, the bulkier analogue of CF3
group) into arenes has long been sought after but remains a formidable task. We herein …