Polyoxometalates on functional substrates: concepts, synergies, and future perspectives

AS Cherevan, SP Nandan, I Roger, R Liu… - Advanced …, 2020 - Wiley Online Library
Polyoxometalates (POMs) are molecular metal oxide clusters that feature a broad range of
structures and functionalities, making them one of the most versatile classes of inorganic …

Polyoxometalates as promising materials for electrochromic devices

SM Wang, J Hwang, E Kim - Journal of Materials Chemistry C, 2019 - pubs.rsc.org
Polyoxometalates (POMs) can act as an electron reservoir, giving rise to mixed-valence
colored state species without their structural changes. This unique feature of POMs has led …

Polyoxometalates-functionalized electrodes for (photo) electrocatalytic applications: Recent advances and prospects

B Fabre, C Falaise, E Cadot - ACS Catalysis, 2022 - ACS Publications
This review is intended to provide an up-to-date and comprehensive description of recent
advances since the mid-2010s in the elaboration and the involvement of polyoxometalates …

A Crown‐Shaped Ru‐Substituted Arsenotungstate for Selective Oxidation of Sulfides with Hydrogen Peroxide

M Han, Y Niu, R Wan, Q Xu, J Lu, P Ma… - … A European Journal, 2018 - Wiley Online Library
An acetate‐bridged Ru‐substituted arsenotungstate [H2N (CH3) 2] 14 [As4W40O140 {Ru2
(CH3COO)} 2]⋅ 22 H2O (1) has been synthesized and structurally characterized. Four Ru …

Tuning the electronic structure of organic–inorganic hybrid polyoxometalates: The crucial role of the covalent linkage

AJ Kibler, GN Newton - Polyhedron, 2018 - Elsevier
The covalent organofunctionalization of polyoxometalates (POMs) has been widely used to
both control and enhance their redox properties, particularly for applications in catalysis …

Regulating the catalytic activity of multi-Ru-bridged polyoxometalates based on differential active site environments with six-coordinate geometry and five-coordinate …

H Li, W Chen, Y Zhao, Y Zou, X Zhao, J Song, P Ma… - Nanoscale, 2021 - pubs.rsc.org
Five-coordinate geometry around ruthenium with highly exposed active sites has attracted
intensive scientific interest due to its superior properties and extensive applications. Herein …

An enhanced antibacterial nanoflowers AgPW@ PDA@ Nisin constructed from polyoxometalate and nisin

C Zhang, M Zhao, H Zou, X Zhang, R Sheng… - Journal of Inorganic …, 2020 - Elsevier
A new composite, AgPW@ PDA@ Nisin, with shell-core structure was successfully
synthesized by a polydopamine (PDA) surfaced conjugated nisin (an antibacterial 34 amino …

Construction of an ultra-sensitive electrochemical sensor based on polyoxometalates decorated with CNTs and AuCo nanoparticles for the voltammetric simultaneous …

Z Bai, N Gao, H Xu, X Wang, L Tan, H Pang, H Ma - Microchimica Acta, 2020 - Springer
A composite modified electrode was prepared based on α-K 7 P 2 VW 17 O 62· 18H 2 O (P 2
W 17 V), CNTs and AuCo nanoparticles (AuCo NPs), and used as a structurally stable and …

Efficient preparation of a nonenzymatic nanoassembly based on cobalt-substituted polyoxometalate and polyethylene imine-capped silver nanoparticles for the …

A Yaqub, SR Gilani, S Bilal, A Hayat, A Asif… - ACS …, 2022 - ACS Publications
The ever-growing exploitation of pesticides and their lethal effects on living beings have
made it a dire need of the day to develop an accurate and reliable approach for their …

Organic–Inorganic Hybrid Films of the Sulfate Dawson Polyoxometalate, [S2W18O62]4–, and Polypyrrole for Iodate Electrocatalysis

A Yaqub, M Vagin, JJ Walsh, F Laffir, I Sakthinathan… - ACS …, 2022 - ACS Publications
The Dawson-type sulfate polyoxometalate (POM)[S2W18O62] 4–has successfully been
entrapped in polypyrrole (PPy) films on glassy carbon electrode (GCE) surfaces through …