Bray–Liebhafsky and non-catalysed Briggs–Rauscher oscillating reactions

G Schmitz, SD Furrow - Russian Journal of Physical Chemistry A, 2016 - Springer
In order to propose mechanisms of complicated chemical systems, it is necessary to study
simpler subsystems. The mechanism we have proposed for the Bray–Liebhafsky (BL) …

Reactions of iodate with iodine in concentrated sulfuric acid. Formation of I (+ 3) and I (+ 1) compounds

G Schmitz, Z Noszticzius, G Hollo, M Wittmann… - Chemical Physics …, 2018 - Elsevier
The absorption spectra in a large range of concentrations show that the reactions of iodate
with iodine in 96% sulfuric acid produce (IO) HSO 4, I 3+ and I 5+, just like in the pure 100 …

Platinum as a HOI/I2 Redox Electrode and Its Mixed Potential in the Oscillatory Briggs–Rauscher Reaction

G Holló, K Kály-Kullai, TB Lawson… - The Journal of …, 2017 - ACS Publications
Pt is a common redox electrode used to follow oscillations qualitatively in the Briggs–
Rauscher (BR) and the Bray–Liebhafsky (BL) reactions from the time of their discovery …

Reexamination of Gas Production in the Bray–Liebhafsky Reaction: What Happened to O2 Pulses?

E Szabo, P Sevcik - The Journal of Physical Chemistry A, 2013 - ACS Publications
Results of high-precision measurements of gas production in the BL reaction are presented,
and an efficient kinetic model for their analysis is proposed. Based on this model, the data …

HOI versus HOIO selectivity of a molten-type AgI electrode

G Holló, K Kály-Kullai, TB Lawson… - The Journal of …, 2014 - ACS Publications
AgI electrode is often applied not only to determine iodine concentration but also to follow
oscillations in the weakly acidic medium of the Bray–Liebhafsky and Briggs–Rauscher …

Iodine volatilisation from the ocean

AJMB Offin - 2024 - figshare.le.ac.uk
Reactive iodine species (RIS) in the troposphere affect partitioning in the HOx and NOx
chemical families and thereby alter the troposphere's oxidising capacity. Recent research …

Halogens

MW Justik - Annual Reports Section" A"(Inorganic Chemistry), 2013 - pubs.rsc.org
Halogens - Annual Reports Section "A" (Inorganic Chemistry) (RSC Publishing) DOI:10.1039/C3IC90014B
Royal Society of Chemistry View PDF VersionPrevious ArticleNext Article DOI: 10.1039/C3IC90014B …

I2O in solution and volatility

SD Furrow, GE Schmitz - Chemical Physics Letters, 2019 - Elsevier
Abstract I (+ 1) formed by reacting iodine with KIO 3 in 96% sulfuric acid is partly in the form
of I 2 O that can be extracted in dichloromethane (DCM). The extraction process is an …

[PDF][PDF] Iodine Inorganic Reactions in Acidic Solutions and Oscillating Reactions

G Schmitz, SD Furrow - Physical Chemistry, 2014 - researchgate.net
In order to propose mechanisms of complicated chemical systems, it is necessary to study
simpler subsystems. The mechanism we have proposed for the Bray-Liebhafsky (BL) …

[PDF][PDF] Kinetics of reactions of iodine inorganic compounds in acidic solutions

G Schmitz, SD Furrow - Physical Chemistry, 2018 - researchgate.net
The kinetics of iodine reactions, as part of the mechanism of the oscillating Bray Liebhafsky
and Briggs Rauscher reactions, is discussed with emphasis on the role of I2O. Preliminary …