Understanding specific ion effects and the Hofmeister series
KP Gregory, GR Elliott, H Robertson, A Kumar… - Physical Chemistry …, 2022 - pubs.rsc.org
Specific ion effects (SIE), encompassing the Hofmeister Series, have been known for more
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …
A comprehensive review of saline water correlations and data: part II—thermophysical properties
This paper reviews the thermophysical properties of saline water correlations and data. The
key parameters that influence the properties are considered, such as multi-component …
key parameters that influence the properties are considered, such as multi-component …
Chemical speciation models based upon the Pitzer activity coefficient equations, including the propagation of uncertainties: Artificial seawater from 0 to 45° C
Accurate chemical speciation models of solutions containing the ions of seawater have
applications in the calculation of carbonate system equilibria and trace metal speciation in …
applications in the calculation of carbonate system equilibria and trace metal speciation in …
Speciation and thermochemical modeling of the ternary system CuSO4–H2SO4–H2O in the temperature range 273.15–373.15 K
In this work, models have been developed that allow to estimate the ionic speciation and
solution properties, such as: water activities, solubilities, densities, and ionic conductivities in …
solution properties, such as: water activities, solubilities, densities, and ionic conductivities in …
Thermochemical and Ionic Speciation Modeling of the Aqueous Sulfuric Acid System Up to 6 Molal and 0–100° C
AN Fuentes, JM Casas - Journal of Solution Chemistry, 2023 - Springer
Abstract Sulfuric acid (H 2 SO 4) is one of the most widely used chemicals, acting as a
reagent in several industries and metallurgy. The chemical behavior in aqueous solutions …
reagent in several industries and metallurgy. The chemical behavior in aqueous solutions …
Modeling the Solution Properties and Mineral–Solution Equilibria in Radionuclide-Bearing Aqueous Nitrate Systems: Application to Binary and Ternary Systems …
A Lassin, S Guignot, A Lach, C Christov… - Journal of Chemical & …, 2020 - ACS Publications
This article focuses on the modeling of the thermodynamic properties of aqueous nitrate
systems that contain radionuclides from low molalities to saturation and occasionally …
systems that contain radionuclides from low molalities to saturation and occasionally …
Modeling the osmotic and activity coefficients of lanthanide nitrate aqueous solutions at 298.15 K from low molalities to supersaturation
S Guignot, A Lassin, C Christov, A Lach… - Journal of Chemical & …, 2018 - ACS Publications
This article is a contribution to the modeling of the thermodynamic properties of 15
lanthanide (including lanthanum)-nitrate aqueous binary solutions, from low molalities to …
lanthanide (including lanthanum)-nitrate aqueous binary solutions, from low molalities to …
Thermodynamics of the Eu (iii)–Mg–SO 4–H 2 O and Eu (iii)–Na–SO 4–H 2 O systems. Part I: solubility experiments and the full dissociation Pitzer model
The solubility of Eu (III) was investigated under undersaturated conditions in acidic, dilute to
concentrated MgSO4 and Na2SO4 solutions at T=(22±2)° C. After attaining equilibrium …
concentrated MgSO4 and Na2SO4 solutions at T=(22±2)° C. After attaining equilibrium …
Modeling hydration of mine tailings: Production of hydraulic binders from alkali-activated materials
The production of alkali-activated materials and geopolymers from the finer fraction of
tailings is being increasingly investigated, as they could be used for building and public …
tailings is being increasingly investigated, as they could be used for building and public …
A quantitative and mechanistic model for the coupling between chemistry and clay hydration
It is proposed here to describe smectite water vapor desorption isotherms using an
exchange formalism that quantitatively accounts for the different hydration states and thus …
exchange formalism that quantitatively accounts for the different hydration states and thus …