Transition metal-mediated C–H bond activation and functionalization represent one of the
most straightforward and powerful tools in modern organic synthetic chemistry. Bi (hetero) …

Palladium-catalyzed aerobic oxidation reactions have been the focus of industrial
application and extensive research efforts for nearly 60 years. A significant transition …

The first photoredox-catalyzed defluoroborylation of polyfluoroarenes with NHC-BH3 has
been facilely achieved at room temperature via a single-electron-transfer (SET)/radical …

Summary Herein, we present (E)-selective transfer semihydrogenation of alkynes based on
an iridium complex in situ generated from [Ir (COD) Cl] 2 and an unsymmetrical (bearing two …

Organic compounds based on (hetero) aryl scaffolds are systems with a wide range of
application, from pharmaceuticals and agrochemicals to semiconducting materials for …

Palladium is a precious metal, which has been widely used for various organic
transformations in the past decades. Currently, the palladium-catalyzed direct activation of …

Pd-catalyzed C–H functionalization reactions of non-directed substrates have recently
emerged as an attractive alternative to the use of directing groups. Key to the success of …

A novel and efficient approach for the synthesis of quinazolines by aerobic photooxidation
with an iodine reagent at room temperature is reported. This method uses harmless visible …

An economical method for the preparation of quinazolines by using singlet oxygen as the
sole oxidant has been developed. The oxidation of primary amines, such as benzylamine …

Polyfluoro (aza) aromatic compounds are of interest in various fields of practical
applications, such as medicinal and agrochemistry, materials science and advanced …