Metal-organic frameworks for catalysis: State of the art, challenges, and opportunities

D Li, HQ Xu, L Jiao, HL Jiang - EnergyChem, 2019 - Elsevier
Abstract Metal-organic frameworks (MOFs), also known as porous coordination polymers
(PCPs), are a unique class of porous crystalline materials that are constructed by metal …

Metal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations

AH Chughtai, N Ahmad, HA Younus… - Chemical Society …, 2015 - pubs.rsc.org
Novel catalytic materials are highly demanded to perform a variety of catalytic organic
reactions. MOFs combine the benefits of heterogeneous catalysis like easy post reaction …

Recent advances in porous polyoxometalate-based metal–organic framework materials

DY Du, JS Qin, SL Li, ZM Su, YQ Lan - Chemical Society Reviews, 2014 - pubs.rsc.org
Polyoxometalate (POM)-based metal–organic framework (MOF) materials contain POM units
and generally generate MOF materials with open networks. POM-based MOF materials …

Dioxygen in polyoxometalate mediated reactions

IA Weinstock, RE Schreiber, R Neumann - Chemical reviews, 2017 - ACS Publications
In this review article, we consider the use of molecular oxygen in reactions mediated by
polyoxometalates. Polyoxometalates are anionic metal oxide clusters of a variety of …

Chromium (III) terephthalate metal organic framework (MIL-101): HF-free synthesis, structure, polyoxometalate composites, and catalytic properties

L Bromberg, Y Diao, H Wu, SA Speakman… - Chemistry of …, 2012 - ACS Publications
Hybrid materials of the metal–organic framework (MOF), chromium (III) terephthalate (MIL-
101), and phosphotungstic acid (PTA) were synthesized in aqueous media in the absence of …

Strategies for incorporating catalytically active polyoxometalates in metal–organic frameworks for organic transformations

CT Buru, OK Farha - ACS applied materials & interfaces, 2020 - ACS Publications
Polyoxometalates (POMs) can benefit from immobilization on solid supports to overcome
their difficulty in processability and stability. Among the reported solid supports, metal …

Incorporating polyoxometalates into a porous MOF greatly improves its selective adsorption of cationic dyes

AX Yan, S Yao, YG Li, ZM Zhang, Y Lu… - … A European Journal, 2014 - Wiley Online Library
Various polyoxometalates (POMs) were successfully immobilized to the mesoporous
coordination polymer MIL‐101 resulting in a series of POM–MOF composite materials …

Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework

CT Buru, P Li, BL Mehdi, A Dohnalkova… - Chemistry of …, 2017 - ACS Publications
A Keggin-type polyoxometalate (H3PW12O40) was incorporated into a mesoporous Zr-
based MOF (NU-1000) via an impregnation method in aqueous media, resulting in the …

Catalytic oxidative desulfurization systems based on Keggin phosphotungstate and metal-organic framework MIL-101

S Ribeiro, ADS Barbosa, AC Gomes, M Pillinger… - Fuel processing …, 2013 - Elsevier
The tetrabutylammonium salt of phosphotungstic acid, TBA 3 PW 12 O 40 (PW 12), has been
encapsulated in the chromium terephthalate metal-organic framework MIL-101 …

H5PV2Mo10O40 Polyoxometalate Encapsulated in NU-1000 Metal–Organic Framework for Aerobic Oxidation of a Mustard Gas Simulant

CT Buru, MC Wasson, OK Farha - ACS Applied Nano Materials, 2019 - ACS Publications
The immobilization of H5PV2Mo10O40 polyoxometalates (POMs) in the in the mesoporous
channel-type metal–organic framework (MOF), NU-1000, via simple impregnation method is …