Significantly enhancing the single-molecule-magnet performance of a dinuclear Dy (III) complex by utilizing an asymmetric auxiliary organic ligand

HS Wang, PF Zhou, J Wang, QQ Long, Z Hu… - Inorganic …, 2021 - ACS Publications
In this work, we employed an asymmetric auxiliary organic ligand (1, 1, 1-
trifluoroacetylacetone, Htfac) to further regulate the magnetic relaxation behavior of series of …

Pressure-controlled magnetism in 2D molecular layers

Y Huang, AK Pathak, JY Tsai, C Rumsey, M Ivill… - Nature …, 2023 - nature.com
Long-range magnetic ordering of two-dimensional crystals can be sensitive to interlayer
coupling, enabling the effective control of interlayer magnetism towards voltage switching …

A hard molecular nanomagnet from confined paramagnetic 3d-4f spins inside a fullerene cage

C Huang, R Sun, L Bao, X Tian, C Pan, M Li… - Nature …, 2023 - nature.com
Reducing inter-spin distance can enhance magnetic interactions and allow for the
realization of outstanding magnetic properties. However, achieving reduced distances is …

Zero-Field SMM Behavior Triggered by Magnetic Exchange Interactions and a Collinear Arrangement of Local Anisotropy Axes in a Linear Co3II Complex

A Zabala-Lekuona, A Landart-Gereka… - Inorganic …, 2023 - ACS Publications
A new linear trinuclear Co (II) 3 complex with a formula of [{Co (μ-L)} 2Co] has been
prepared by self-assembly of Co (II) ions and the N3O3-tripodal Schiff base ligand H3L …

A Zn-based Zig-Zag 1D chain type coordination polymer for removal of methylene blue dye from an aqueous solution

S Waseem, H Saleem, MN Akhtar, M Imran… - Inorganica Chimica …, 2024 - Elsevier
A 1D zig-zag zinc coordination chain,[Zn (piv) 2] n (1)(where piv= pivalic acid) has been
synthesized by a reaction of ZnCl 2 with O-donor pivalic acid in the mixed solvent system …

Butterfly-like Heteronuclear 3d–4f Metal Clusters: Synthesis, Structures, Magnetic Properties, and Magnetocaloric Effect

MN Akhtar, MA AlDamen, M Fitta, M Shahid… - Crystal Growth & …, 2021 - ACS Publications
This study describes the self-assembled synthesis, characterization, and structural features
of two new heterometallic Fe6Ln clusters,[Fe6Ln (μ3-OH) 2 (mdea) 6 (N3) 6 (NO3)](Ln= Y …

The first exploration of coordination chemistry using a methyl substituted o-vanillin based ligand: an example starting with Dy 4/Zn 2 Dy 2 systems displaying slow …

A Panja, Z Jagličić, R Herchel, P Brandão… - New Journal of …, 2022 - pubs.rsc.org
The literature has witnessed the exceptionally rich coordination chemistry, ranging from
monomeric species to coordination polymers, generated by the Schiff base ligands derived …

High nuclearity heterometallic [Fe7Ln4] neutral coordination clusters with electrocatalytic activity for water oxidation

MN Akhtar, MA AlDamen, R Bikas, Z Shaghaghi… - International Journal of …, 2024 - Elsevier
Three mixed metal iron-lanthanide isostructural clusters formulated,[Fe 7 Ln 4 (μ 4-O) 3 (μ 3-
O)(μ 3-OH) 2 (μ 2-OH)(mdea) 6 (κ 1-OAc)(κ 2-OAc) 3 (μ-OAc) 6 (H 2 O)]. nH 2 O where {n …

Zinc-based solvents free coordination complexes: Synthesis, structures, photoluminous properties, DFT calculations and Hirshfeld surface analysis

H Saleem, MN Akhtar, R Bikas, N Heydari… - Journal of Molecular …, 2023 - Elsevier
Two novel Zn (II) complexes,[Zn (2-MeImi) 2 (benz) 2](1) and [Zn (2-MeImi) 2 (piv) 2](2) were
prepared by the reaction of Zn (NO 3) 2· 6H 2 O with 2-methylimidazole (2-MeImi) and …

Single-molecule magnet behavior in heterometallic decanuclear [Ln 2 Fe 8](Ln= Y, Dy, Ho, Tb, Gd) coordination clusters

MT Chen, HX Zhao, LS Long, LS Zheng - Dalton Transactions, 2024 - pubs.rsc.org
Five decanuclear lanthanide–iron clusters, formulated as [Ln2Fe8 (hmp) 10 (μ2-OH) 4 (μ3-
OH) 2 (μ4-O) 4 (H2O) 6]· 6ClO4· xH2O (x≈ 8, Ln= Y for 1; x≈ 6, Ln= Dy for 2; x≈ 6, Ln= Ho …