Benefits of using multiple Raman laser wavelengths for characterizing defects in a UO2 matrix

S Karcher, R Mohun, T Olds, M Weber… - Journal of Raman …, 2022 - Wiley Online Library
Raman spectroscopy is one of the most useful techniques for studying the structure of UO2
and changes due to specific defects caused by doping, changes in stoichiometry, irradiation …

Nucleation mechanisms and speciation of metal oxide clusters

E Petrus, M Segado, C Bo - Chemical Science, 2020 - pubs.rsc.org
The self-assembly mechanisms of polyoxometalates (POMs) are still a matter of discussion
owing to the difficult task of identifying all the chemical species and reactions involved. We …

Annealing of the Raman defect peaks in He-implanted UO2

L Desgranges, A Canizares, P Simon - Journal of Nuclear Materials, 2022 - Elsevier
The exploitation of the data acquired by Raman spectroscopy on UO 2 related materials
requires the understanding of the so-called defect peaks. To do so, we measured the …

Uranyl ammonium carbonate precipitation and conversion into triuranium octaoxide

NT Hung, LB Thuan, NT Thuy, HS Than, D Van Phuc… - Heliyon, 2024 - cell.com
Uranyl ammonium carbonate (AUC), with the chemical formula UO 2 CO 3· 2 (NH 4) 2 CO 3,
plays a crucial role in the wet conversion of uranium hexafluoride (UF 6) into uranium …

A novel method to stably secure beryllium resources for fusion blankets

JH Kim, S Nakano, M Nakamichi - Journal of Nuclear Materials, 2020 - Elsevier
A demonstration (DEMO) fusion reactor will require a huge amount of beryllium (Be) with
approximately 490 tons. Since the total production of Be in the world, for now, is …

Unlocking phase diagrams for molybdenum and tungsten nanoclusters and prediction of their formation constants

E Petrus, C Bo - The Journal of Physical Chemistry A, 2021 - ACS Publications
Understanding and controlling aqueous speciation of metal oxides are key for the discovery
and development of novel materials, and challenge both experimental and computational …

Trace Impurities Identified as Forensic Signatures in CMX-5 Fuel Pellets Using X-ray Spectroscopic Techniques

A van Veelen, SM Hickam, NP Edwards… - Analytical …, 2022 - ACS Publications
Small-particle analysis is a highly promising emerging forensic tool for analysis of interdicted
special nuclear materials. Integration of microstructural, morphological, compositional, and …

Impacts of trace level chromium on formation of superoxide within uranyl triperoxide complexes

SK Scherrer, H Rajapaksha, DV Kravchuk… - Chemical …, 2024 - pubs.rsc.org
U (VI) peroxides are important within the nuclear fuel cycle, but reactive oxygen species
(ROS) can form upon oxidation. Herein, we identified the spectral signatures of a U (VI) …

Rare earth elements in Uranium ore for nuclear forensic application

SOO John, IT Usman, TC Akpa… - IOP Conference Series …, 2021 - iopscience.iop.org
The contents of the Lanthanides, which are Rare Earth Elements (REE), that show
consistent patterns under changing geochemical conditions in uranium ore have been …

Structural features of early fuel cycle taggant incorporation for intentional nuclear forensics

TL Spano, TN Beiswenger, BT Manard, TL Ulrich… - Journal of Nuclear …, 2024 - Elsevier
To develop strategies for incorporating transition metal taggants (Fe, Cr, and Ni) into oxide
fuels and to understand how these taggant candidates persist through early fuel cycle …