Although the high efficiency of the homogeneous processes, using rhodium or iridium
complexes, was clearly demonstrated industrially, heterogeneous catalysts offer the …

The carbonylation of methanol to give acetic acid is one of the most important
homogeneously catalyzed industrial processes. The original [Rh (CO) 2I2]− catalyst …

In the past few decades, the advances of CO2 reduction have been mostly focused on the
synthesis of C1 products, such as CO, formic acid, methanol, and methane. However, the …

Oxidative methane (CH4) carbonylation promises a direct route to the synthesis of value-
added oxygenates such as acetic acid (CH3COOH). Here, we report a strategy to realize …

The utility of carbazole in photo-, electro-, and medicinal applications has ensured its
widespread use also as the backbone in tridentate pincer ligands. In this review, the aim is …

A palladium-catalyzed iodine atom transfer cycloisomerization of (Z)-1-iodo-1, 6-diene has
been developed, which provides a facile method to construct six-memebered heterocycles …

This paper deals with the synthesis of rhodium (I) Vaska-type complexes of the general form
trans-[Rh (CO) X (PX3)](X= halide, X aryl or alkyl substituent) when incorporating tertiary …

The carbonylation of methanol to acetic acid is established as one of the major industrial
applications of homogeneous catalysis. Since the introduction of a rhodium-catalyzed …

The development of chelating diphosphine ligands has been a prolific research area for
several decades, but quite surprisingly, from the plethora of diphosphines that are currently …

Acetic acid synthesis via the carbonylation of methanol is one of the most important
industrial applications of catalysis using organometallic compounds. All the group 9 metals …