Heterolytic Dissociation of H2 in Heterogeneous Catalysis

DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …

Reversible Pd Catalysts Supported on Hierarchical Titanate Nanosheets for an N-Methylindole-Based Liquid Organic Hydrogen Carrier

J Lee, BG Park, K Sung, H Lee, J Kim, E Nam… - ACS …, 2023 - ACS Publications
Reversible hydrogenation and dehydrogenation processes were investigated in a liquid
organic hydrogen carrier (LOHC) system by employing a single-catalyst approach. Key …

Design of gold catalysts for activation of H 2 and H-donor molecules: transfer hydrogenation and CO 2 hydrogenation

JL Fiorio, LR Borges, T Neves-Garcia… - Catalysis Science & …, 2023 - pubs.rsc.org
Catalytic activation of dihydrogen (H2) on metal surfaces allowed the development of very
important industrial hydrogenation processes and plays also an important role in the context …

Theoretical Insights into H2 Activation over Anatase TiO2 Supported Metal Adatoms

Q Li, G Yan, DG Vlachos - ACS Catalysis, 2024 - ACS Publications
H2 activation is fundamental in catalysis. Single-atom catalysts (SACs) can be highly
selective hydrogenation catalysts due to their tunable geometric and electronic properties. In …

[HTML][HTML] Heterolytic dissociation of H2 and bond activation: Spotting new opportunities from a unified view

Y Jing, Y Wang - Chem Catalysis, 2023 - cell.com
Catalytic hydrogenation/hydrogenolysis always involves the dissociation of H 2 and the
activation of substrate. H 2 can be dissociated via homolytic and heterolytic pathways. The …

Potassium as the best alkali metal promoter in boosting the hydrogenation activity of Ru/MgO for aromatic LOHC molecules by facilitated heterolytic H2 adsorption

TW Kim, D Kim, Y Jo, HJ Jung, JH Park, YW Suh - Journal of Catalysis, 2023 - Elsevier
Alkali metals (AM) are frequently used as promoters in a number of reactions. In aromatic
hydrogenation over Ru/MgO, their basicity may promote heterolytic H 2 adsorption, thereby …

Engineering a Ni1Fe1–ZnO Interface to Boost Selective Hydrogenation of Methyl Stearate to Octadecanol

T Zhang, H Yan, Z Liu, W Zhan, H Yu, Y Liao, Y Liu… - ACS …, 2022 - ACS Publications
Tailoring the hydrodeoxygenation capacity via construction of metal–support interfaces is
still a significant challenge for hydrogenation of oxygenated substrates. Herein, we boosted …

Electronic vs. Geometric effects of Al2O3-supported Ru species on the adsorption of H2 and substrate for aromatic LOHC hydrogenation

TW Kim, HJ Chun, Y Jo, D Kim, H Ko, SH Kim, SK Kim… - Journal of …, 2023 - Elsevier
The intrinsic rate of aromatic hydrogenation is tuned by electronic and geometric characters
of active metals. Herein, Ru/Al 2 O 3 catalysts were prepared by varying the Ru loading from …

Sustainable Production of Chemicals via Hydrotreating of CO2 and Biomass Derived Molecules Using Heterogeneous Noble Metal Oxide Catalysts

E Naranov - ChemCatChem, 2024 - Wiley Online Library
The noble metals are widely used in heterogeneous catalysis and automobile industry. The
limited natural sources and high cost of noble metals dictates improving the efficiency of …

Advanced heterolytic H2 adsorption of K-added Ru/MgO catalysts for accelerating hydrogen storage into aromatic benzyltoluenes

TW Kim, H Jeong, Y Jo, D Kim, JH Park, SK Kim… - Journal of Energy …, 2022 - Elsevier
Herein, we report a highly active K-added Ru/MgO catalyst for hydrogen storage into
aromatic benzyltoluenes at low temperatures to advance liquid organic hydrogen carrier …